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Article: A rearranged hydroperoxide from the reduction of artemisinin

TitleA rearranged hydroperoxide from the reduction of artemisinin
Authors
Sy, LKHui, SMCheung, KKBrown, GD
Issue Date1997
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tet
Citation
Tetrahedron, 1997, v. 53 n. 22, p. 7493-7500 How to Cite?
DOI: http://dx.doi.org/10.1016/S0040-4020(97)00444-4
AbstractLithium aluminium hydride reduction of artemisinin produces two unexpected rearrangement products in addition to those reported previously. The structure of the major rearrangement product, a tertiary hydroperoxide, was determined by 2D-NMR and chemical reactions. A mechanism is proposed for this rearrangement, based on the observation that dihydroartemisinin can also be converted into the same hydroperoxide in alkaline solution.
Persistent Identifierhttp://hdl.handle.net/10722/167568
ISSN
0040-4020
2021 Impact Factor: 2.388
2020 SCImago Journal Rankings: 0.581
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorSy, LKen_US
dc.contributor.authorHui, SMen_US
dc.contributor.authorCheung, KKen_US
dc.contributor.authorBrown, GDen_US
dc.date.accessioned2012-10-08T03:08:35Z-
dc.date.available2012-10-08T03:08:35Z-
dc.date.issued1997en_US
dc.identifier.citationTetrahedron, 1997, v. 53 n. 22, p. 7493-7500en_US
dc.identifier.issn0040-4020en_US
dc.identifier.urihttp://hdl.handle.net/10722/167568-
dc.description.abstractLithium aluminium hydride reduction of artemisinin produces two unexpected rearrangement products in addition to those reported previously. The structure of the major rearrangement product, a tertiary hydroperoxide, was determined by 2D-NMR and chemical reactions. A mechanism is proposed for this rearrangement, based on the observation that dihydroartemisinin can also be converted into the same hydroperoxide in alkaline solution.en_US
dc.languageengen_US
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/teten_US
dc.relation.ispartofTetrahedronen_US
dc.titleA rearranged hydroperoxide from the reduction of artemisininen_US
dc.typeArticleen_US
dc.identifier.emailSy, LK:sylk@hkucc.hku.hken_US
dc.identifier.authoritySy, LK=rp00784en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0040-4020(97)00444-4en_US
dc.identifier.scopuseid_2-s2.0-0030989209en_US
dc.identifier.hkuros25300-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0030989209&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume53en_US
dc.identifier.issue22en_US
dc.identifier.spage7493en_US
dc.identifier.epage7500en_US
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridSy, LK=35874602700en_US
dc.identifier.scopusauthoridHui, SM=7202831749en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.scopusauthoridBrown, GD=7406468149en_US
dc.identifier.issnl0040-4020-

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