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Article: When electron exchange is chemical exchange-assignment of 1H NMR spectra of paramagnetic cobalt(II)-2,2′ :6′ ,2″-terpyridine complexes

TitleWhen electron exchange is chemical exchange-assignment of 1H NMR spectra of paramagnetic cobalt(II)-2,2′ :6′ ,2″-terpyridine complexes
Authors
Chow, HSConstable, ECHousecroft, CEKulicke, KJTao, Y
Issue Date2005
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Dalton Transactions, 2005 n. 2, p. 236-237 How to Cite?
DOI: http://dx.doi.org/10.1039/b415419c
AbstractCobalt(II) complexes of oligopyridine and related ligands were analyzed in context of dynamic combinatorial libraries. It was found that the kinetic lability of the d cobalt(II) center combined with the strength of the Co-N bonds allowed the construction of thermodynamically stable libraries of complexes from the reaction of cobalt(II) salts with mixture of ligands. It was observed that H NMR spectra of these complexes were paramagnetically shifted and were characteristic of the individual complexes. It was shown that exchange rates were within the area of medium to slow chemical exchange on the NMR spectroscopy time scale.
Persistent Identifierhttp://hdl.handle.net/10722/167888
ISSN
1477-9226
2021 Impact Factor: 4.569
2020 SCImago Journal Rankings: 0.980
ISI Accession Number ID
WOS:000225889400003
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorChow, HSen_US
dc.contributor.authorConstable, ECen_US
dc.contributor.authorHousecroft, CEen_US
dc.contributor.authorKulicke, KJen_US
dc.contributor.authorTao, Yen_US
dc.date.accessioned2012-10-08T03:12:33Z-
dc.date.available2012-10-08T03:12:33Z-
dc.date.issued2005en_US
dc.identifier.citationDalton Transactions, 2005 n. 2, p. 236-237en_US
dc.identifier.issn1477-9226en_US
dc.identifier.urihttp://hdl.handle.net/10722/167888-
dc.description.abstractCobalt(II) complexes of oligopyridine and related ligands were analyzed in context of dynamic combinatorial libraries. It was found that the kinetic lability of the d cobalt(II) center combined with the strength of the Co-N bonds allowed the construction of thermodynamically stable libraries of complexes from the reaction of cobalt(II) salts with mixture of ligands. It was observed that H NMR spectra of these complexes were paramagnetically shifted and were characteristic of the individual complexes. It was shown that exchange rates were within the area of medium to slow chemical exchange on the NMR spectroscopy time scale.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofDalton Transactionsen_US
dc.titleWhen electron exchange is chemical exchange-assignment of 1H NMR spectra of paramagnetic cobalt(II)-2,2′ :6′ ,2″-terpyridine complexesen_US
dc.typeArticleen_US
dc.identifier.emailChow, HS:hoishanc@hku.hken_US
dc.identifier.authorityChow, HS=rp00682en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/b415419cen_US
dc.identifier.pmid15616710-
dc.identifier.scopuseid_2-s2.0-12444319338en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-12444319338&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue2en_US
dc.identifier.spage236en_US
dc.identifier.epage237en_US
dc.identifier.isiWOS:000225889400003-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChow, HS=8056499800en_US
dc.identifier.scopusauthoridConstable, EC=7005405466en_US
dc.identifier.scopusauthoridHousecroft, CE=34770925800en_US
dc.identifier.scopusauthoridKulicke, KJ=6508292217en_US
dc.identifier.scopusauthoridTao, Y=8056500200en_US
dc.identifier.issnl1477-9226-

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