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Article: Molecular orbital studies of luminescent silver(I) chalcogenido clusters [Ag4(μ-dppm)4(μ4-E)]2+ (dppm = Ph2PCH2PPh2)

TitleMolecular orbital studies of luminescent silver(I) chalcogenido clusters [Ag4(μ-dppm)4(μ4-E)]2+ (dppm = Ph2PCH2PPh2)
Authors
Wang, CRLo, KKWYam, VWW
Issue Date1997
Citation
Journal Of The Chemical Society - Dalton Transactions, 1997 n. 2, p. 227-229 How to Cite?
AbstractThe electronic structures of the μ4-chalcogenido silver(I) complexes [Ag4(μ-dppm)4(μ4-E)] [O3SCF3]2 (E = S 1, Se 2 or Te 3; dppm = Ph2PCH2PPh2) have been calculated by use of the Fenske-Hall molecular orbital method. The results indicate that complexes 1-3 show similar electronic structures, with the highest occupied molecular orbital being mainly of Ag-E character while the lowest unoccupied molecular orbital is of metal-metal interaction character. A correlation between the results of these calculations with the spectroscopic properties of this class of complexes is described.
Persistent Identifierhttp://hdl.handle.net/10722/168044
ISSN
0300-9246
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorWang, CRen_US
dc.contributor.authorLo, KKWen_US
dc.contributor.authorYam, VWWen_US
dc.date.accessioned2012-10-08T03:14:30Z-
dc.date.available2012-10-08T03:14:30Z-
dc.date.issued1997en_US
dc.identifier.citationJournal Of The Chemical Society - Dalton Transactions, 1997 n. 2, p. 227-229en_US
dc.identifier.issn0300-9246en_US
dc.identifier.urihttp://hdl.handle.net/10722/168044-
dc.description.abstractThe electronic structures of the μ4-chalcogenido silver(I) complexes [Ag4(μ-dppm)4(μ4-E)] [O3SCF3]2 (E = S 1, Se 2 or Te 3; dppm = Ph2PCH2PPh2) have been calculated by use of the Fenske-Hall molecular orbital method. The results indicate that complexes 1-3 show similar electronic structures, with the highest occupied molecular orbital being mainly of Ag-E character while the lowest unoccupied molecular orbital is of metal-metal interaction character. A correlation between the results of these calculations with the spectroscopic properties of this class of complexes is described.en_US
dc.languageengen_US
dc.relation.ispartofJournal of the Chemical Society - Dalton Transactionsen_US
dc.titleMolecular orbital studies of luminescent silver(I) chalcogenido clusters [Ag4(μ-dppm)4(μ4-E)]2+ (dppm = Ph2PCH2PPh2)en_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-33748603468en_US
dc.identifier.hkuros25801-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33748603468&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue2en_US
dc.identifier.spage227en_US
dc.identifier.epage229en_US
dc.identifier.scopusauthoridWang, CR=9242250400en_US
dc.identifier.scopusauthoridLo, KKW=26032181200en_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.issnl0300-9246-

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