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Article: Resonance raman study of the short-time photodissociation dynamics of the a-band absorption of cyclopropyl iodide in cyclohexane solution

TitleResonance raman study of the short-time photodissociation dynamics of the a-band absorption of cyclopropyl iodide in cyclohexane solution
Authors
Zheng, XLi, YLPhillips, DL
Issue Date2004
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca
Citation
Journal Of Physical Chemistry A, 2004, v. 108 n. 39, p. 8032-8039 How to Cite?
DOI: http://dx.doi.org/10.1021/jp0492772
AbstractResonance Raman spectra were obtained for cyclopropyl iodide in cyclohexane solution with excitation wavelengths in resonance with the A-band absorption spectrum. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal C-I stretch and nominal C-C-I deformation normal modes accompanied by moderate motion along the nominal cyclopropyl ring breathing and ring deformation normal modes. A preliminary resonance Raman intensity analysis was done, and the results for cyclopropyl iodide were compared to previously reported results for several cyclic and noncyclic alkyl iodides.
Persistent Identifierhttp://hdl.handle.net/10722/168368
ISSN
1089-5639
2021 Impact Factor: 2.944
2020 SCImago Journal Rankings: 0.756
ISI Accession Number ID
WOS:000224071600035
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorZheng, Xen_US
dc.contributor.authorLi, YLen_US
dc.contributor.authorPhillips, DLen_US
dc.date.accessioned2012-10-08T03:18:03Z-
dc.date.available2012-10-08T03:18:03Z-
dc.date.issued2004en_US
dc.identifier.citationJournal Of Physical Chemistry A, 2004, v. 108 n. 39, p. 8032-8039en_US
dc.identifier.issn1089-5639en_US
dc.identifier.urihttp://hdl.handle.net/10722/168368-
dc.description.abstractResonance Raman spectra were obtained for cyclopropyl iodide in cyclohexane solution with excitation wavelengths in resonance with the A-band absorption spectrum. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal C-I stretch and nominal C-C-I deformation normal modes accompanied by moderate motion along the nominal cyclopropyl ring breathing and ring deformation normal modes. A preliminary resonance Raman intensity analysis was done, and the results for cyclopropyl iodide were compared to previously reported results for several cyclic and noncyclic alkyl iodides.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpcaen_US
dc.relation.ispartofJournal of Physical Chemistry Aen_US
dc.titleResonance raman study of the short-time photodissociation dynamics of the a-band absorption of cyclopropyl iodide in cyclohexane solutionen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/jp0492772en_US
dc.identifier.scopuseid_2-s2.0-6344294243en_US
dc.identifier.hkuros98482-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-6344294243&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume108en_US
dc.identifier.issue39en_US
dc.identifier.spage8032en_US
dc.identifier.epage8039en_US
dc.identifier.isiWOS:000224071600035-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridZheng, X=7404090253en_US
dc.identifier.scopusauthoridLi, YL=27168456500en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.issnl1089-5639-

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