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- Scopus: eid_2-s2.0-0000076247
- WOS: WOS:A1997WY69400008
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Article: [Pt-2(PPh3)(4)(mu-S)(2)] as a metalloligand toward main-group Lewis acids. Crystal structures and bonding analysis of two low-coordinate BiCl3 adducts [Pt-2(PPh3)(4)(mu(3)-S)(2)BiCl3] and [Pt-2(PPh3)(4)(mu(3)-S)(2)BiCl2]PF6
Title | [Pt-2(PPh3)(4)(mu-S)(2)] as a metalloligand toward main-group Lewis acids. Crystal structures and bonding analysis of two low-coordinate BiCl3 adducts [Pt-2(PPh3)(4)(mu(3)-S)(2)BiCl3] and [Pt-2(PPh3)(4)(mu(3)-S)(2)BiCl2]PF6 |
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Authors | |
Keywords | Aggregate Bismuth Heterometallic Metalloligand Platinum Sulfide |
Issue Date | 1997 |
Citation | Polyhedron, 1997, v. 16, n. 14, p. 2381-2386 How to Cite? |
Abstract | Addition of BiCl3 to [Pt2(PPh3)4(μ-S)2] gives [Pt2(PPh3)4(μ3-S) 2BiCl3], which undergoes dissociation and metathesis with NH4PF6 to give [Pt2(PPh3)4(μ3-S) 2BiCl2]PF6. An X-ray single-crystal diffraction analysis established two highly distorted square-pyramidal and tetrahedral structures, respectively. The four- and five-coordination numbers are unusually low among the known BiIII halide adducts. Fenske-Hall MO analysis offers an explanation to the structural characteristics with reference to the stereochemically active lone pairs, coordination numbers, uneven Bi - Cl and Bi - S lengths and the butterfly geometry of the {Pt2S2} core. These parameters are compared with those of the other intermetallics previously reported. @ 1997 Elsevier Science Ltd. |
Persistent Identifier | http://hdl.handle.net/10722/219345 |
ISSN | 2021 Impact Factor: 2.975 2020 SCImago Journal Rankings: 0.496 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Zhou, Mei Sheng | - |
dc.contributor.author | Tan, Agnes L. | - |
dc.contributor.author | Xu, Yan | - |
dc.contributor.author | Lam, Choon Fui | - |
dc.contributor.author | Leung, Pak Hing | - |
dc.contributor.author | Mok, K. F. | - |
dc.contributor.author | Koh, Lip Lin | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:56:50Z | - |
dc.date.available | 2015-09-23T02:56:50Z | - |
dc.date.issued | 1997 | - |
dc.identifier.citation | Polyhedron, 1997, v. 16, n. 14, p. 2381-2386 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219345 | - |
dc.description.abstract | Addition of BiCl3 to [Pt2(PPh3)4(μ-S)2] gives [Pt2(PPh3)4(μ3-S) 2BiCl3], which undergoes dissociation and metathesis with NH4PF6 to give [Pt2(PPh3)4(μ3-S) 2BiCl2]PF6. An X-ray single-crystal diffraction analysis established two highly distorted square-pyramidal and tetrahedral structures, respectively. The four- and five-coordination numbers are unusually low among the known BiIII halide adducts. Fenske-Hall MO analysis offers an explanation to the structural characteristics with reference to the stereochemically active lone pairs, coordination numbers, uneven Bi - Cl and Bi - S lengths and the butterfly geometry of the {Pt2S2} core. These parameters are compared with those of the other intermetallics previously reported. @ 1997 Elsevier Science Ltd. | - |
dc.language | eng | - |
dc.relation.ispartof | Polyhedron | - |
dc.subject | Aggregate | - |
dc.subject | Bismuth | - |
dc.subject | Heterometallic | - |
dc.subject | Metalloligand | - |
dc.subject | Platinum | - |
dc.subject | Sulfide | - |
dc.title | [Pt-2(PPh3)(4)(mu-S)(2)] as a metalloligand toward main-group Lewis acids. Crystal structures and bonding analysis of two low-coordinate BiCl3 adducts [Pt-2(PPh3)(4)(mu(3)-S)(2)BiCl3] and [Pt-2(PPh3)(4)(mu(3)-S)(2)BiCl2]PF6 | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0277-5387(96)00580-3 | - |
dc.identifier.scopus | eid_2-s2.0-0000076247 | - |
dc.identifier.volume | 16 | - |
dc.identifier.issue | 14 | - |
dc.identifier.spage | 2381 | - |
dc.identifier.epage | 2386 | - |
dc.identifier.isi | WOS:A1997WY69400008 | - |
dc.identifier.issnl | 0277-5387 | - |