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Article: Crystallographic identification of an unusual homoleptic palladium citrate [Na(OH2)6]·{[Na3(OH2) 8]3[NaPd3(C6H4O 7)3]2}·(H2O) stabilised by intermetallic aggregation with sodium and heavy hydration

TitleCrystallographic identification of an unusual homoleptic palladium citrate [Na(OH2)6]·{[Na3(OH2) 8]3[NaPd3(C6H4O 7)3]2}·(H2O) stabilised by intermetallic aggregation with sodium and heavy hydration
Authors
Gunari, ParagKrishnasamy, SureshBai, Shi QiangHor, T. S Andy
Issue Date2010
Citation
Dalton Transactions, 2010, v. 39, n. 40, p. 9462-9464 How to Cite?
DOI: http://dx.doi.org/10.1039/c0dt00273a
AbstractA rare precious metal binary citrate represented by palladium in the form of a water-rich Na-Pd intermetallic aggregate has been isolated and crystallographically characterised. It shows a penta-anionic [NaPd 3(citrate)3]5- core balanced by [Na 3]3+ and Na+ hydrates in a 3-D coordination network stabilised exclusively by citrate bridges and fortified by extensive H-bonding. © 2010 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219638
ISSN
1477-9226
2021 Impact Factor: 4.569
2020 SCImago Journal Rankings: 0.980
ISI Accession Number ID
WOS:000282516500003

 

DC FieldValueLanguage
dc.contributor.authorGunari, Parag-
dc.contributor.authorKrishnasamy, Suresh-
dc.contributor.authorBai, Shi Qiang-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:35Z-
dc.date.available2015-09-23T02:57:35Z-
dc.date.issued2010-
dc.identifier.citationDalton Transactions, 2010, v. 39, n. 40, p. 9462-9464-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219638-
dc.description.abstractA rare precious metal binary citrate represented by palladium in the form of a water-rich Na-Pd intermetallic aggregate has been isolated and crystallographically characterised. It shows a penta-anionic [NaPd 3(citrate)3]5- core balanced by [Na 3]3+ and Na+ hydrates in a 3-D coordination network stabilised exclusively by citrate bridges and fortified by extensive H-bonding. © 2010 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleCrystallographic identification of an unusual homoleptic palladium citrate [Na(OH2)6]·{[Na3(OH2) 8]3[NaPd3(C6H4O 7)3]2}·(H2O) stabilised by intermetallic aggregation with sodium and heavy hydration-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c0dt00273a-
dc.identifier.pmid20945544-
dc.identifier.scopuseid_2-s2.0-77957668688-
dc.identifier.volume39-
dc.identifier.issue40-
dc.identifier.spage9462-
dc.identifier.epage9464-
dc.identifier.eissn1477-9234-
dc.identifier.isiWOS:000282516500003-
dc.identifier.issnl1477-9226-

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