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- Publisher Website: 10.1039/c3dt50247c
- Scopus: eid_2-s2.0-84880636842
- PMID: 23817835
- WOS: WOS:000321910000034
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Article: Hybrid NS ligands supported Cu(i)/(ii) complexes for azide-alkyne cycloaddition reactions
| Title | Hybrid NS ligands supported Cu(i)/(ii) complexes for azide-alkyne cycloaddition reactions |
|---|---|
| Authors | |
| Issue Date | 2013 |
| Citation | Dalton Transactions, 2013, v. 42, n. 31, p. 11319-11326 How to Cite? |
| Abstract | Three copper complexes of nitrogen-sulfur donor ligands, [CuBr 2(L1)] (1), [CuCl2(L2)2] (2) and [Cu 2I2(L3)]n (3) (L1 = bis(2- cyclohexylsulfanylethyl)amine, L2 = 2-(benzylsulfanylmethyl)pyridine and L3 = 2-(4-pyridylsulfanylmethyl)pyridine), have been synthesized and characterized by single-crystal X-ray diffraction (XRD), powder XRD and TGA analysis. Complexes 1 and 2 are mononuclear Cu(ii) complexes and are EPR active with distorted square-pyramidal and octahedral geometry, respectively. Complex 3 is a two-dimensional tetrahedral Cu(i) coordination polymer with 16- and 20-membered metallocycles. These complexes show good catalytic activities for one-pot azide-alkyne cycloaddition reactions in CH3OH-H2O. © 2013 The Royal Society of Chemistry. |
| Persistent Identifier | http://hdl.handle.net/10722/219707 |
| ISSN | 2021 Impact Factor: 4.569 2020 SCImago Journal Rankings: 0.980 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Bai, Shi Qiang | - |
| dc.contributor.author | Jiang, Lu | - |
| dc.contributor.author | Zuo, Jing Lin | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:57:46Z | - |
| dc.date.available | 2015-09-23T02:57:46Z | - |
| dc.date.issued | 2013 | - |
| dc.identifier.citation | Dalton Transactions, 2013, v. 42, n. 31, p. 11319-11326 | - |
| dc.identifier.issn | 1477-9226 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219707 | - |
| dc.description.abstract | Three copper complexes of nitrogen-sulfur donor ligands, [CuBr 2(L1)] (1), [CuCl2(L2)2] (2) and [Cu 2I2(L3)]n (3) (L1 = bis(2- cyclohexylsulfanylethyl)amine, L2 = 2-(benzylsulfanylmethyl)pyridine and L3 = 2-(4-pyridylsulfanylmethyl)pyridine), have been synthesized and characterized by single-crystal X-ray diffraction (XRD), powder XRD and TGA analysis. Complexes 1 and 2 are mononuclear Cu(ii) complexes and are EPR active with distorted square-pyramidal and octahedral geometry, respectively. Complex 3 is a two-dimensional tetrahedral Cu(i) coordination polymer with 16- and 20-membered metallocycles. These complexes show good catalytic activities for one-pot azide-alkyne cycloaddition reactions in CH3OH-H2O. © 2013 The Royal Society of Chemistry. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Dalton Transactions | - |
| dc.title | Hybrid NS ligands supported Cu(i)/(ii) complexes for azide-alkyne cycloaddition reactions | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1039/c3dt50247c | - |
| dc.identifier.pmid | 23817835 | - |
| dc.identifier.scopus | eid_2-s2.0-84880636842 | - |
| dc.identifier.volume | 42 | - |
| dc.identifier.issue | 31 | - |
| dc.identifier.spage | 11319 | - |
| dc.identifier.epage | 11326 | - |
| dc.identifier.eissn | 1477-9234 | - |
| dc.identifier.isi | WOS:000321910000034 | - |
| dc.identifier.issnl | 1477-9226 | - |