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- Publisher Website: 10.1002/anie.201509996
- Scopus: eid_2-s2.0-84956827984
- PMID: 26611496
- WOS: WOS:000368069200061
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Article: Ligand-Promoted Borylation of C(sp3)-H Bonds with Palladium(II) Catalysts
| Title | Ligand-Promoted Borylation of C(sp3)-H Bonds with Palladium(II) Catalysts |
|---|---|
| Authors | |
| Keywords | C-H activation amino acids borylation palladium synthetic methods |
| Issue Date | 2016 |
| Citation | Angewandte Chemie - International Edition, 2016, v. 55, n. 2, p. 785-789 How to Cite? |
| Abstract | © 2016 Wiley-VCH Verlag GmbH & Co. KGaA. A quinoline-based ligand effectively promotes the palladium-catalyzed borylation of C(sp3)-H bonds. Primary β-C(sp3)-H bonds in carboxylic acid derivatives as well as secondary C(sp3)-H bonds in a variety of carbocyclic rings, including cyclopropanes, cyclobutanes, cyclopentanes, cyclohexanes, and cycloheptanes, can thus be borylated. This directed borylation method complements existing iridium(I)- and rhodium(I)-catalyzed C-H borylation reactions in terms of scope and operational conditions. |
| Persistent Identifier | http://hdl.handle.net/10722/276502 |
| ISSN | 2021 Impact Factor: 16.823 2020 SCImago Journal Rankings: 5.831 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | He, Jian | - |
| dc.contributor.author | Jiang, Heng | - |
| dc.contributor.author | Takise, Ryosuke | - |
| dc.contributor.author | Zhu, Ru Yi | - |
| dc.contributor.author | Chen, Gang | - |
| dc.contributor.author | Dai, Hui Xiong | - |
| dc.contributor.author | Dhar, T. G.Murali | - |
| dc.contributor.author | Shi, Jun | - |
| dc.contributor.author | Zhang, Hao | - |
| dc.contributor.author | Cheng, Peter T.W. | - |
| dc.contributor.author | Yu, Jin Quan | - |
| dc.date.accessioned | 2019-09-18T08:33:48Z | - |
| dc.date.available | 2019-09-18T08:33:48Z | - |
| dc.date.issued | 2016 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2016, v. 55, n. 2, p. 785-789 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/276502 | - |
| dc.description.abstract | © 2016 Wiley-VCH Verlag GmbH & Co. KGaA. A quinoline-based ligand effectively promotes the palladium-catalyzed borylation of C(sp3)-H bonds. Primary β-C(sp3)-H bonds in carboxylic acid derivatives as well as secondary C(sp3)-H bonds in a variety of carbocyclic rings, including cyclopropanes, cyclobutanes, cyclopentanes, cyclohexanes, and cycloheptanes, can thus be borylated. This directed borylation method complements existing iridium(I)- and rhodium(I)-catalyzed C-H borylation reactions in terms of scope and operational conditions. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | C-H activation | - |
| dc.subject | amino acids | - |
| dc.subject | borylation | - |
| dc.subject | palladium | - |
| dc.subject | synthetic methods | - |
| dc.title | Ligand-Promoted Borylation of C(sp3)-H Bonds with Palladium(II) Catalysts | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.201509996 | - |
| dc.identifier.pmid | 26611496 | - |
| dc.identifier.scopus | eid_2-s2.0-84956827984 | - |
| dc.identifier.volume | 55 | - |
| dc.identifier.issue | 2 | - |
| dc.identifier.spage | 785 | - |
| dc.identifier.epage | 789 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:000368069200061 | - |
| dc.identifier.issnl | 1433-7851 | - |