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Conference Paper: Applications of Epoxy and Aziridinyl Enolsilanes in Intramolecular (4+3) and (3+2) Cycloadditions

TitleApplications of Epoxy and Aziridinyl Enolsilanes in Intramolecular (4+3) and (3+2) Cycloadditions
Authors
Chiu, PZheng, YChen, Y
Issue Date2019
Citation
102nd Canadian Chemistry Conference and Exhibition, Quebec City, Canada, 3-7 June 2019 How to Cite?
AbstractEpoxy and aziridinyl enolsilanes react as dienophiles in intramolecular (4+3) cycloadditions with typically challenging dienes such as pyrroles, thiophenes and benzenes. They also react as enophiles in intramolecular (3+2) reactions with dienes and alkenes. The reactions proceed through activated epoxides and aziridines as intermediates and therefore the cycloadducts can be obtained with high ee.
DescriptionOral Session - Part of: (OR Division) - A Symposium in Honour of Mark Lautens’ 60th Birthday
Persistent Identifierhttp://hdl.handle.net/10722/282732

 

DC FieldValueLanguage
dc.contributor.authorChiu, P-
dc.contributor.authorZheng, Y-
dc.contributor.authorChen, Y-
dc.date.accessioned2020-06-01T06:40:39Z-
dc.date.available2020-06-01T06:40:39Z-
dc.date.issued2019-
dc.identifier.citation102nd Canadian Chemistry Conference and Exhibition, Quebec City, Canada, 3-7 June 2019-
dc.identifier.urihttp://hdl.handle.net/10722/282732-
dc.descriptionOral Session - Part of: (OR Division) - A Symposium in Honour of Mark Lautens’ 60th Birthday-
dc.description.abstractEpoxy and aziridinyl enolsilanes react as dienophiles in intramolecular (4+3) cycloadditions with typically challenging dienes such as pyrroles, thiophenes and benzenes. They also react as enophiles in intramolecular (3+2) reactions with dienes and alkenes. The reactions proceed through activated epoxides and aziridines as intermediates and therefore the cycloadducts can be obtained with high ee.-
dc.languageeng-
dc.relation.ispartof102nd Canadian Chemistry Conference and Exhibition-
dc.titleApplications of Epoxy and Aziridinyl Enolsilanes in Intramolecular (4+3) and (3+2) Cycloadditions-
dc.typeConference_Paper-
dc.identifier.emailChiu, P: pchiu@hku.hk-
dc.identifier.authorityChiu, P=rp00680-
dc.identifier.hkuros305409-

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