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Article: Rational tuning of the rigidity of a ligand scaffold: synthesis of diphenylsulfide-linked bis(oxazoline) ligands and their application in asymmetric allylic alkylation

TitleRational tuning of the rigidity of a ligand scaffold: synthesis of diphenylsulfide-linked bis(oxazoline) ligands and their application in asymmetric allylic alkylation
Authors
Du, XianLiu, HanDu, Da Ming
Issue Date2010
Citation
Tetrahedron Asymmetry, 2010, v. 21, n. 2, p. 241-246 How to Cite?
DOI: http://dx.doi.org/10.1016/j.tetasy.2010.01.015
AbstractThe scaffold rigidity of bis(oxazoline) ligands was rationally tuned on the basis of literature information. Diphenylsulfide-linked bis(oxazoline) ligands with a flexible scaffold were efficiently synthesized to test our hypothesis. The improved enantioselectivity in palladium-catalyzed asymmetric allylic alkylation reaction was achieved as we expected. © 2010 Elsevier Ltd. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/291952
ISSN
0957-4166
2016 Impact Factor: 2.126
2020 SCImago Journal Rankings: 0.396
ISI Accession Number ID
WOS:000276083200019

 

DC FieldValueLanguage
dc.contributor.authorDu, Xian-
dc.contributor.authorLiu, Han-
dc.contributor.authorDu, Da Ming-
dc.date.accessioned2020-11-17T14:55:27Z-
dc.date.available2020-11-17T14:55:27Z-
dc.date.issued2010-
dc.identifier.citationTetrahedron Asymmetry, 2010, v. 21, n. 2, p. 241-246-
dc.identifier.issn0957-4166-
dc.identifier.urihttp://hdl.handle.net/10722/291952-
dc.description.abstractThe scaffold rigidity of bis(oxazoline) ligands was rationally tuned on the basis of literature information. Diphenylsulfide-linked bis(oxazoline) ligands with a flexible scaffold were efficiently synthesized to test our hypothesis. The improved enantioselectivity in palladium-catalyzed asymmetric allylic alkylation reaction was achieved as we expected. © 2010 Elsevier Ltd. All rights reserved.-
dc.languageeng-
dc.relation.ispartofTetrahedron Asymmetry-
dc.titleRational tuning of the rigidity of a ligand scaffold: synthesis of diphenylsulfide-linked bis(oxazoline) ligands and their application in asymmetric allylic alkylation-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.tetasy.2010.01.015-
dc.identifier.scopuseid_2-s2.0-77949541229-
dc.identifier.volume21-
dc.identifier.issue2-
dc.identifier.spage241-
dc.identifier.epage246-
dc.identifier.eissn1362-511X-
dc.identifier.isiWOS:000276083200019-
dc.identifier.issnl0957-4166-

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