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Article: Direct experimental evidence for the priority of flexible ligand skeleton in asymmetric friedel-crafts alkylation of indole with nitroalkenes

TitleDirect experimental evidence for the priority of flexible ligand skeleton in asymmetric friedel-crafts alkylation of indole with nitroalkenes
Authors
Liu, HanWang, Neng DongDu, Da Ming
KeywordsDiphenylamine
Friedel-crafts alkylation
Bis(oxazoline)
Dihydroacridine
Flexible scaffold
Rigid scaffold
Issue Date2010
Citation
Letters in Organic Chemistry, 2010, v. 7, n. 2, p. 114-120 How to Cite?
DOI: http://dx.doi.org/10.2174/157017810790796354
AbstractDirect experimental evidence for the priority of flexible ligand skeleton in asymmetric Friedel-Crafts alkylation was obtained through XRD analysis of flexible ligand/ZnCl2 complex, as well as synthesis of dihydroacridine-linked bis(oxazoline) ligands with planar rigid scaffold. A transition state model without NH φ interaction was proposed for the rigid ligands to interpret the inversion of absolute configuration. © 2010 Bentham Science Publishers Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/291962
ISSN
1570-1786
2021 Impact Factor: 0.797
2020 SCImago Journal Rankings: 0.180
ISI Accession Number ID
WOS:000275168000006

 

DC FieldValueLanguage
dc.contributor.authorLiu, Han-
dc.contributor.authorWang, Neng Dong-
dc.contributor.authorDu, Da Ming-
dc.date.accessioned2020-11-17T14:55:28Z-
dc.date.available2020-11-17T14:55:28Z-
dc.date.issued2010-
dc.identifier.citationLetters in Organic Chemistry, 2010, v. 7, n. 2, p. 114-120-
dc.identifier.issn1570-1786-
dc.identifier.urihttp://hdl.handle.net/10722/291962-
dc.description.abstractDirect experimental evidence for the priority of flexible ligand skeleton in asymmetric Friedel-Crafts alkylation was obtained through XRD analysis of flexible ligand/ZnCl2 complex, as well as synthesis of dihydroacridine-linked bis(oxazoline) ligands with planar rigid scaffold. A transition state model without NH φ interaction was proposed for the rigid ligands to interpret the inversion of absolute configuration. © 2010 Bentham Science Publishers Ltd.-
dc.languageeng-
dc.relation.ispartofLetters in Organic Chemistry-
dc.subjectDiphenylamine-
dc.subjectFriedel-crafts alkylation-
dc.subjectBis(oxazoline)-
dc.subjectDihydroacridine-
dc.subjectFlexible scaffold-
dc.subjectRigid scaffold-
dc.titleDirect experimental evidence for the priority of flexible ligand skeleton in asymmetric friedel-crafts alkylation of indole with nitroalkenes-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.2174/157017810790796354-
dc.identifier.scopuseid_2-s2.0-77951482907-
dc.identifier.volume7-
dc.identifier.issue2-
dc.identifier.spage114-
dc.identifier.epage120-
dc.identifier.isiWOS:000275168000006-
dc.identifier.issnl1570-1786-

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