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Article: Synthesis and X-ray crystal structure of cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)]

TitleSynthesis and X-ray crystal structure of cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)]
Authors
Wong, WKJiang, TKwong, DWJWong, WT
Issue Date1995
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1995, v. 14 n. 12, p. 1695-1697 How to Cite?
DOI: http://dx.doi.org/10.1016/0277-5387(95)00117-B
AbstractThe interaction of (Ph2PN)C(Ph)[N(SiMe3)2] with one equivalent of C7H8Cr(CO)4 in diethyl ether gave cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)] in good yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods. The NH proton of the bidentate iminophosphine ligand undergoes facile deuterium exchange with D2O at ambient temperature. A 1,3-silyl shift mechanism has been proposed for the formation of the product.
Persistent Identifierhttp://hdl.handle.net/10722/69517
ISSN
0277-5387
2021 Impact Factor: 2.975
2020 SCImago Journal Rankings: 0.496

 

DC FieldValueLanguage
dc.contributor.authorWong, WKen_HK
dc.contributor.authorJiang, Ten_HK
dc.contributor.authorKwong, DWJen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:14:23Z-
dc.date.available2010-09-06T06:14:23Z-
dc.date.issued1995en_HK
dc.identifier.citationPolyhedron, 1995, v. 14 n. 12, p. 1695-1697en_HK
dc.identifier.issn0277-5387en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69517-
dc.description.abstractThe interaction of (Ph2PN)C(Ph)[N(SiMe3)2] with one equivalent of C7H8Cr(CO)4 in diethyl ether gave cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)] in good yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods. The NH proton of the bidentate iminophosphine ligand undergoes facile deuterium exchange with D2O at ambient temperature. A 1,3-silyl shift mechanism has been proposed for the formation of the product.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_HK
dc.relation.ispartofPolyhedronen_HK
dc.titleSynthesis and X-ray crystal structure of cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=14&issue=2&spage=1695&epage=1697&date=1995&atitle=Synthesis+and+X-ray+crystal+structure+of+cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)]en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0277-5387(95)00117-B-
dc.identifier.scopuseid_2-s2.0-58149364559-
dc.identifier.hkuros14698en_HK
dc.identifier.volume14-
dc.identifier.issue12-
dc.identifier.spage1695-
dc.identifier.epage1697-
dc.publisher.placeNetherlands-
dc.identifier.issnl0277-5387-

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