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Article: The x-ray structure, electrochemistry and catalytic reactivity of Os4Au(µ-H)3)(CO)12(PPh3) towards the oxidative carbonylation of aniline

TitleThe x-ray structure, electrochemistry and catalytic reactivity of Os4Au(µ-H)3)(CO)12(PPh3) towards the oxidative carbonylation of aniline
Authors
Li, YPan, WXWong, WT
KeywordsOsmium-gold
Electrochemistry
Oxidative carbonylation
Aniline
Issue Date2002
PublisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278
Citation
Journal of Cluster Science, 2002, v. 13 n. 2, p. 223-233 How to Cite?
DOI: http://dx.doi.org/10.1023/A:1015500118973
AbstractThe reaction of the anion [Os4(μ-H)3(CO)12]− with one equivalent of Au(PPh3)Cl affords [Os4Au(μ-H)3(CO)12(PPh3)] (1), the structure of which was established by single crystal X-ray analysis. Its electrochemical behavior and catalytic properties are also reported. This bimetallic cluster catalyses the oxidative carbonylation of aniline to give methyl phenylcarbamate in methanol with good conversion and selectivity compared to the homometallic [Os4(μ-H)4(CO)12] cluster.
Persistent Identifierhttp://hdl.handle.net/10722/70476
ISSN
1040-7278
2021 Impact Factor: 3.447
2020 SCImago Journal Rankings: 0.405
ISI Accession Number ID
WOS:000175715300005

 

DC FieldValueLanguage
dc.contributor.authorLi, Yen_HK
dc.contributor.authorPan, WXen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:23:14Z-
dc.date.available2010-09-06T06:23:14Z-
dc.date.issued2002en_HK
dc.identifier.citationJournal of Cluster Science, 2002, v. 13 n. 2, p. 223-233en_HK
dc.identifier.issn1040-7278en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70476-
dc.description.abstractThe reaction of the anion [Os4(μ-H)3(CO)12]− with one equivalent of Au(PPh3)Cl affords [Os4Au(μ-H)3(CO)12(PPh3)] (1), the structure of which was established by single crystal X-ray analysis. Its electrochemical behavior and catalytic properties are also reported. This bimetallic cluster catalyses the oxidative carbonylation of aniline to give methyl phenylcarbamate in methanol with good conversion and selectivity compared to the homometallic [Os4(μ-H)4(CO)12] cluster.-
dc.languageengen_HK
dc.publisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278en_HK
dc.relation.ispartofJournal of Cluster Scienceen_HK
dc.rightsThe original publication is available at www.springerlink.com-
dc.subjectOsmium-gold-
dc.subjectElectrochemistry-
dc.subjectOxidative carbonylation-
dc.subjectAniline-
dc.titleThe x-ray structure, electrochemistry and catalytic reactivity of Os4Au(µ-H)3)(CO)12(PPh3) towards the oxidative carbonylation of anilineen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1040-7278&volume=13&issue=2&spage=223&epage=233&date=2002&atitle=The+x-ray+structure,+electrochemistry+and+catalytic+reactivity+of+Os4Au(m-H)3)(CO)12(PPh3)+towards+the+oxidative+carbonylation+of+anilineen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1023/A:1015500118973-
dc.identifier.scopuseid_2-s2.0-0036015315-
dc.identifier.hkuros68273en_HK
dc.identifier.volume13-
dc.identifier.issue2-
dc.identifier.spage223-
dc.identifier.epage233-
dc.identifier.isiWOS:000175715300005-
dc.publisher.placeUnited States-
dc.identifier.issnl1040-7278-

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