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Article: Structural preference in complexes containing both double-face and single-face π-acceptor ligands
Title | Structural preference in complexes containing both double-face and single-face π-acceptor ligands |
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Authors | |
Keywords | Competition For Π-Backdonation Metal-Alkene Complexes Metal-Alkenyl Complexes Metal-Boryl Complexes Metal-Silane Complexes |
Issue Date | 2001 |
Publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem |
Citation | Journal Of Organometallic Chemistry, 2001, v. 635 n. 1-2, p. 84-91 How to Cite? |
Abstract | The development of the Dewar-Chatt-Duncanson model has a great impact on coordination/organometallic chemistry in terms of understanding the structure and bonding in metal complexes containing π-accepting ligands. The majority of π-acceptor ligands can be categorized into two types: double-face and single-face π-accepting ligands. Metal complexes containing both single-face and double-face π-accepting ligands show unique structural preferences. In this paper, the structural consequence for these complexes will be discussed with the aid of density functional theory calculations. Examples include η1-alkenyl, η2-silane, η2-alkene and boryl octahedral complexes. © 2001 Elsevier Science B.V. |
Persistent Identifier | http://hdl.handle.net/10722/167827 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
References |
DC Field | Value | Language |
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dc.contributor.author | Han Lam, W | en_US |
dc.contributor.author | Lin, Z | en_US |
dc.date.accessioned | 2012-10-08T03:12:00Z | - |
dc.date.available | 2012-10-08T03:12:00Z | - |
dc.date.issued | 2001 | en_US |
dc.identifier.citation | Journal Of Organometallic Chemistry, 2001, v. 635 n. 1-2, p. 84-91 | en_US |
dc.identifier.issn | 0022-328X | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167827 | - |
dc.description.abstract | The development of the Dewar-Chatt-Duncanson model has a great impact on coordination/organometallic chemistry in terms of understanding the structure and bonding in metal complexes containing π-accepting ligands. The majority of π-acceptor ligands can be categorized into two types: double-face and single-face π-accepting ligands. Metal complexes containing both single-face and double-face π-accepting ligands show unique structural preferences. In this paper, the structural consequence for these complexes will be discussed with the aid of density functional theory calculations. Examples include η1-alkenyl, η2-silane, η2-alkene and boryl octahedral complexes. © 2001 Elsevier Science B.V. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem | en_US |
dc.relation.ispartof | Journal of Organometallic Chemistry | en_US |
dc.subject | Competition For Π-Backdonation | en_US |
dc.subject | Metal-Alkene Complexes | en_US |
dc.subject | Metal-Alkenyl Complexes | en_US |
dc.subject | Metal-Boryl Complexes | en_US |
dc.subject | Metal-Silane Complexes | en_US |
dc.title | Structural preference in complexes containing both double-face and single-face π-acceptor ligands | en_US |
dc.type | Article | en_US |
dc.identifier.email | Han Lam, W:chsue@hku.hk | en_US |
dc.identifier.authority | Han Lam, W=rp00719 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/S0022-328X(01)00816-6 | en_US |
dc.identifier.scopus | eid_2-s2.0-0042871280 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0042871280&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 635 | en_US |
dc.identifier.issue | 1-2 | en_US |
dc.identifier.spage | 84 | en_US |
dc.identifier.epage | 91 | en_US |
dc.publisher.place | Switzerland | en_US |
dc.identifier.scopusauthorid | Han Lam, W=26642862800 | en_US |
dc.identifier.scopusauthorid | Lin, Z=7404230177 | en_US |
dc.identifier.issnl | 0022-328X | - |