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- Publisher Website: 10.1016/0022-328X(87)83028-0
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Article: Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses
Title | Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses |
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Authors | |
Issue Date | 1987 |
Citation | Journal of Organometallic Chemistry, 1987, v. 319, n. 2, p. 213-217 How to Cite? |
Abstract | Trimethylamine N-oxide (TMNO)-initiated decarbonylations of Mo(CO)6 followed by phosphine additions yield the complexes Mo(CO)5(Ph2PCH2PPh2), which consists of a unidentate diphosphine, and the dinuclear phosphine-bridged complexes Mo2(CO)10(μ-Ph2P(CH2)nPPh2) (where n = 2, 3) at ambient temperatures. The IR and NMR (1H and 31P) spectroscopic and structural properties of these complexes are presented and discussed. Some thermal analytical data are summarised. © 1987. |
Persistent Identifier | http://hdl.handle.net/10722/219810 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:58:00Z | - |
dc.date.available | 2015-09-23T02:58:00Z | - |
dc.date.issued | 1987 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 1987, v. 319, n. 2, p. 213-217 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/10722/219810 | - |
dc.description.abstract | Trimethylamine N-oxide (TMNO)-initiated decarbonylations of Mo(CO)6 followed by phosphine additions yield the complexes Mo(CO)5(Ph2PCH2PPh2), which consists of a unidentate diphosphine, and the dinuclear phosphine-bridged complexes Mo2(CO)10(μ-Ph2P(CH2)nPPh2) (where n = 2, 3) at ambient temperatures. The IR and NMR (1H and 31P) spectroscopic and structural properties of these complexes are presented and discussed. Some thermal analytical data are summarised. © 1987. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Organometallic Chemistry | - |
dc.title | Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/0022-328X(87)83028-0 | - |
dc.identifier.scopus | eid_2-s2.0-0010850417 | - |
dc.identifier.volume | 319 | - |
dc.identifier.issue | 2 | - |
dc.identifier.spage | 213 | - |
dc.identifier.epage | 217 | - |
dc.identifier.isi | WOS:A1987F729500008 | - |
dc.identifier.issnl | 0022-328X | - |