File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/acscatal.0c04199
- Scopus: eid_2-s2.0-85097751275
- WOS: WOS:000608850500002
Supplementary
- Citations:
- Appears in Collections:
Article: FMPhos: Expanding the catalytic capacity of small-bite-angle bisphosphine ligands in regioselective alkene hydrofunctionalizations
Title | FMPhos: Expanding the catalytic capacity of small-bite-angle bisphosphine ligands in regioselective alkene hydrofunctionalizations |
---|---|
Authors | |
Keywords | Alkene hydrofunctionalization Bisphosphine ligand Bite angle Regioselectivity |
Issue Date | 2020 |
Citation | ACS Catalysis, 2020, v. 10, n. 24, p. 14349-14358 How to Cite? |
Abstract | In contrast to the plethora of large-bite-angle bisphosphine ligands available to transition-metal catalysis, the development of small-bite-angle bisphosphine ligands has suffered from the limited structural variations accessible on their single-atom-containing backbones. Herein, we report the design and applications of a discrete very small bite-angle bisphosphine ligand, namely, FMPhos. Featuring a fluorene−methylene unit appended on the single-carbon linker, the ligand harbors an unusually rigid backbone that presumably stabilizes its complexation with transition metals during catalysis. Compared with the known dppm ligand, it exhibited superior reactivity and regioselectivity in a number of alkene hydrofunctionalization reactions, catalyzed by iridium and rhodium. |
Persistent Identifier | http://hdl.handle.net/10722/327720 |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chen, Xiao Yang | - |
dc.contributor.author | Zhou, Xukai | - |
dc.contributor.author | Wang, Jianchun | - |
dc.contributor.author | Dong, Guangbin | - |
dc.date.accessioned | 2023-04-24T05:09:29Z | - |
dc.date.available | 2023-04-24T05:09:29Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | ACS Catalysis, 2020, v. 10, n. 24, p. 14349-14358 | - |
dc.identifier.uri | http://hdl.handle.net/10722/327720 | - |
dc.description.abstract | In contrast to the plethora of large-bite-angle bisphosphine ligands available to transition-metal catalysis, the development of small-bite-angle bisphosphine ligands has suffered from the limited structural variations accessible on their single-atom-containing backbones. Herein, we report the design and applications of a discrete very small bite-angle bisphosphine ligand, namely, FMPhos. Featuring a fluorene−methylene unit appended on the single-carbon linker, the ligand harbors an unusually rigid backbone that presumably stabilizes its complexation with transition metals during catalysis. Compared with the known dppm ligand, it exhibited superior reactivity and regioselectivity in a number of alkene hydrofunctionalization reactions, catalyzed by iridium and rhodium. | - |
dc.language | eng | - |
dc.relation.ispartof | ACS Catalysis | - |
dc.subject | Alkene hydrofunctionalization | - |
dc.subject | Bisphosphine ligand | - |
dc.subject | Bite angle | - |
dc.subject | Regioselectivity | - |
dc.title | FMPhos: Expanding the catalytic capacity of small-bite-angle bisphosphine ligands in regioselective alkene hydrofunctionalizations | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/acscatal.0c04199 | - |
dc.identifier.scopus | eid_2-s2.0-85097751275 | - |
dc.identifier.volume | 10 | - |
dc.identifier.issue | 24 | - |
dc.identifier.spage | 14349 | - |
dc.identifier.epage | 14358 | - |
dc.identifier.eissn | 2155-5435 | - |
dc.identifier.isi | WOS:000608850500002 | - |