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Article: Λ-Type doubling parameters for molecules in Δ electronic states

TitleΛ-Type doubling parameters for molecules in Δ electronic states
Authors
Brown, JMCheung, ASCMerer, AJ
Issue Date1987
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmsp
Citation
Journal Of Molecular Spectroscopy, 1987, v. 124 n. 2, p. 464-475 How to Cite?
DOI: http://dx.doi.org/10.1016/0022-2852(87)90157-3
AbstractAn effective Hamiltonian has been developed for the Λ doubling in Δ electronic states, and its matrix elements are given for Δ states up to quintet spin multiplicity. The number of determinable Λ doubling parameters, in the absence of centrifugal distortion effects, is equal to the spin multiplicity up to 2S + 1 = 5, and is 5 for higher multiplicities. As in Π electronic states, the Λ doubling in case (a) Δ states will be roughly proportional to [J(J + 1)] Ω, with Ω = 0 states being split into 0 + and 0 - components even at zero rotation. General expressions are given for the parameters. © 1987.
Persistent Identifierhttp://hdl.handle.net/10722/147709
ISSN
0022-2852
2023 Impact Factor: 1.4
2023 SCImago Journal Rankings: 0.374
ISI Accession Number ID
WOS:A1987J777400018

 

DC FieldValueLanguage
dc.contributor.authorBrown, JMen_HK
dc.contributor.authorCheung, ASCen_HK
dc.contributor.authorMerer, AJen_HK
dc.date.accessioned2012-05-29T06:08:50Z-
dc.date.available2012-05-29T06:08:50Z-
dc.date.issued1987en_HK
dc.identifier.citationJournal Of Molecular Spectroscopy, 1987, v. 124 n. 2, p. 464-475en_HK
dc.identifier.issn0022-2852en_HK
dc.identifier.urihttp://hdl.handle.net/10722/147709-
dc.description.abstractAn effective Hamiltonian has been developed for the Λ doubling in Δ electronic states, and its matrix elements are given for Δ states up to quintet spin multiplicity. The number of determinable Λ doubling parameters, in the absence of centrifugal distortion effects, is equal to the spin multiplicity up to 2S + 1 = 5, and is 5 for higher multiplicities. As in Π electronic states, the Λ doubling in case (a) Δ states will be roughly proportional to [J(J + 1)] Ω, with Ω = 0 states being split into 0 + and 0 - components even at zero rotation. General expressions are given for the parameters. © 1987.en_HK
dc.languageengen_US
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmspen_HK
dc.relation.ispartofJournal of Molecular Spectroscopyen_HK
dc.titleΛ-Type doubling parameters for molecules in Δ electronic statesen_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/0022-2852(87)90157-3-
dc.identifier.scopuseid_2-s2.0-0001545236en_HK
dc.identifier.volume124en_HK
dc.identifier.issue2en_HK
dc.identifier.spage464en_HK
dc.identifier.epage475en_HK
dc.identifier.isiWOS:A1987J777400018-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridBrown, JM=7409449073en_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK
dc.identifier.scopusauthoridMerer, AJ=6603864922en_HK
dc.identifier.issnl0022-2852-

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