Shear bond strength of Bis-GMA resin and methacrylated dendrimer resins on silanized titanium substrate

Abstract

Objectives: The study compared the bond strengths of three resins, Bis-GMA and two novel experimental methacrylated polyester dendrimer resins to grit-blasted titanium substrate with three silanes. Methods: Two commercial dental silanes (ESPE Sil™ and Monobond-S™) and an experimental 0.5vol% 3-methacryloxypropyltrimethoxysilane were applied to grit-blasted Ti substrates. Light-polymerizable resins of Bis-GMA and methacrylated dendrimer were applied to the grit-blasted Ti substrate with polyethylene molds. The substrates with resin stubs (n=10) were thermocycled (6000cycles, 5-55 °C) or kept in water (37 °C, 24 h). The shear bond strength of the resin was measured at a crosshead speed of 1.0 mm min-1. The surface examination, before and after silanization, was made with a scanning electron microscope (SEM). The silane reactions on the Ti surface were monitored by Fourier transform infrared spectrometry. Results: Statistical analysis (ANOVA) showed that the highest shear bond for thermocycled samples was obtained for Bis-GMA with Monobond-S™ (19.4 MPa, standard deviation (SD) 7.1 MPa), and after water storage with a laboratory-made silane (26.4 MPa, SD 8.1 MPa). The dendrimer and Bis-GMA resins conferred equal bonding properties to grit-blasted titanium after thermocycling. The silane, resin type, and storage conditions significantly affected the shear bond strength (p<0.001 for all factors). SEM images suggested a mainly cohesive type of bonding failure. Significance: A dendrimer based resin and the Bis-GMA resin systems conferred statistically equivalent bonding properties to silica-coated Ti after thermocycling. © 2004 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.