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Article: Luminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide
Title | Luminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide |
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Authors | |
Issue Date | 1994 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
Citation | Polyhedron, 1994, v. 13 n. 6-7, p. 887-890 How to Cite? |
Abstract | The reaction of [Au(CCPh]∞ with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(μ2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular AuċAu separations are 3.083(2) and 3.167(2) Å. At room temperature, the [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. © 1994. |
Persistent Identifier | http://hdl.handle.net/10722/167291 |
ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Yip, HK | en_US |
dc.contributor.author | Lo, WC | en_US |
dc.contributor.author | Peng, SM | en_US |
dc.date.accessioned | 2012-10-08T03:05:20Z | - |
dc.date.available | 2012-10-08T03:05:20Z | - |
dc.date.issued | 1994 | en_US |
dc.identifier.citation | Polyhedron, 1994, v. 13 n. 6-7, p. 887-890 | en_US |
dc.identifier.issn | 0277-5387 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167291 | - |
dc.description.abstract | The reaction of [Au(CCPh]∞ with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(μ2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular AuċAu separations are 3.083(2) and 3.167(2) Å. At room temperature, the [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. © 1994. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_US |
dc.relation.ispartof | Polyhedron | en_US |
dc.title | Luminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/S0277-5387(00)83005-3 | - |
dc.identifier.scopus | eid_2-s2.0-0000696515 | en_US |
dc.identifier.volume | 13 | en_US |
dc.identifier.issue | 6-7 | en_US |
dc.identifier.spage | 887 | en_US |
dc.identifier.epage | 890 | en_US |
dc.identifier.isi | WOS:A1994NE63500005 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Yip, HK=15068942100 | en_US |
dc.identifier.scopusauthorid | Lo, WC=7201502447 | en_US |
dc.identifier.scopusauthorid | Peng, SM=35464852200 | en_US |
dc.identifier.issnl | 0277-5387 | - |