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Article: Six- and seven-coordinated manganese(II) complexes of quaterpyridine. Synthesis, X-ray crystal structure and catalyst for alkene epoxidation
Title | Six- and seven-coordinated manganese(II) complexes of quaterpyridine. Synthesis, X-ray crystal structure and catalyst for alkene epoxidation |
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Authors | |
Issue Date | 1993 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
Citation | Polyhedron, 1993, v. 12 n. 18, p. 2169-2173 How to Cite? |
Abstract | Reaction of Mn(ClO4)2 · xH2O and Mn(CH3CO2)3 · xH2O with 2.2′ : 6′,2″ : 6″,2′″-quaterpyridine (QP) in acetonitrile or methanol gave the complexes [Mn(QP)(H2O)2] (ClO4)2 and [Mn(QP)(CH3CO2)(H2O)](ClO4), respectively. X-ray crystal structure determination revealed that the manganese atom is six-coordinated in the former, but seven-coordinated in the latter. Both complexes catalysed oxidation of alkenes by PhIO. © 1993. |
Persistent Identifier | http://hdl.handle.net/10722/167293 |
ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Chan, CW | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Peng, SM | en_US |
dc.date.accessioned | 2012-10-08T03:05:21Z | - |
dc.date.available | 2012-10-08T03:05:21Z | - |
dc.date.issued | 1993 | en_US |
dc.identifier.citation | Polyhedron, 1993, v. 12 n. 18, p. 2169-2173 | en_US |
dc.identifier.issn | 0277-5387 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167293 | - |
dc.description.abstract | Reaction of Mn(ClO4)2 · xH2O and Mn(CH3CO2)3 · xH2O with 2.2′ : 6′,2″ : 6″,2′″-quaterpyridine (QP) in acetonitrile or methanol gave the complexes [Mn(QP)(H2O)2] (ClO4)2 and [Mn(QP)(CH3CO2)(H2O)](ClO4), respectively. X-ray crystal structure determination revealed that the manganese atom is six-coordinated in the former, but seven-coordinated in the latter. Both complexes catalysed oxidation of alkenes by PhIO. © 1993. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_US |
dc.relation.ispartof | Polyhedron | en_US |
dc.title | Six- and seven-coordinated manganese(II) complexes of quaterpyridine. Synthesis, X-ray crystal structure and catalyst for alkene epoxidation | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/S0277-5387(00)88253-4 | - |
dc.identifier.scopus | eid_2-s2.0-0000709237 | en_US |
dc.identifier.volume | 12 | en_US |
dc.identifier.issue | 18 | en_US |
dc.identifier.spage | 2169 | en_US |
dc.identifier.epage | 2173 | en_US |
dc.identifier.isi | WOS:A1993MB63900001 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Chan, CW=7404814723 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Peng, SM=35464852200 | en_US |
dc.identifier.issnl | 0277-5387 | - |