File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1016/0277-5387(95)00425-4
- Scopus: eid_2-s2.0-0001195318
- WOS: WOS:A1996UA24400015
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Luminescent silver(I) cluster, synthesis, spectroscopic properties and X-ray crystal structure of [Ag 3CPh) 2(dppm) 3]Cl · 4Et 2O · H 2O {dppm = bis(diphenylphosphino)methane}
Title | Luminescent silver(I) cluster, synthesis, spectroscopic properties and X-ray crystal structure of [Ag 3CPh) 2(dppm) 3]Cl · 4Et 2O · H 2O {dppm = bis(diphenylphosphino)methane} |
---|---|
Authors | |
Issue Date | 1996 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
Citation | Polyhedron, 1996, v. 15 n. 11, p. 1853-1858 How to Cite? |
Abstract | The [Ag 3(μ 3-η 2-C≡CCPh) 2(dppm) 3] + complex {dppm = bis(diphenylphosphino)methane} was prepared by reacting [(RC≡C)Ag]∞ with dppm in CH 2Cl 2. The X-ray crystal structure of [Ag 3(μ 3-η 2-C≡CPh) 2(dppm) 3]Cl · 4Et 2O · H 2O has been determined. The complex has an isosceles triangular array of Ag atoms and with two asymmetric phenylacetylide caps. The intramolecular Ag (I) ⋯ Ag (I) separations are 2.866(2) and 2.983(1) Å. Extended-Hückel molecular-orbital calculation reveals that the HOMO comprises of contributions from Ag(I) and phenylacetylide whereas the LUMO is largely the π* of phenylacetylide. The complex shows a solid-state emission at 555 nm with a lifetime of 0.4 μs at room temperature. |
Persistent Identifier | http://hdl.handle.net/10722/167327 |
ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Wang, CF | en_US |
dc.contributor.author | Peng, SM | en_US |
dc.contributor.author | Chan, CK | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:05:43Z | - |
dc.date.available | 2012-10-08T03:05:43Z | - |
dc.date.issued | 1996 | en_US |
dc.identifier.citation | Polyhedron, 1996, v. 15 n. 11, p. 1853-1858 | en_US |
dc.identifier.issn | 0277-5387 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167327 | - |
dc.description.abstract | The [Ag 3(μ 3-η 2-C≡CCPh) 2(dppm) 3] + complex {dppm = bis(diphenylphosphino)methane} was prepared by reacting [(RC≡C)Ag]∞ with dppm in CH 2Cl 2. The X-ray crystal structure of [Ag 3(μ 3-η 2-C≡CPh) 2(dppm) 3]Cl · 4Et 2O · H 2O has been determined. The complex has an isosceles triangular array of Ag atoms and with two asymmetric phenylacetylide caps. The intramolecular Ag (I) ⋯ Ag (I) separations are 2.866(2) and 2.983(1) Å. Extended-Hückel molecular-orbital calculation reveals that the HOMO comprises of contributions from Ag(I) and phenylacetylide whereas the LUMO is largely the π* of phenylacetylide. The complex shows a solid-state emission at 555 nm with a lifetime of 0.4 μs at room temperature. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_US |
dc.relation.ispartof | Polyhedron | en_US |
dc.title | Luminescent silver(I) cluster, synthesis, spectroscopic properties and X-ray crystal structure of [Ag 3CPh) 2(dppm) 3]Cl · 4Et 2O · H 2O {dppm = bis(diphenylphosphino)methane} | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/0277-5387(95)00425-4 | en_US |
dc.identifier.scopus | eid_2-s2.0-0001195318 | en_US |
dc.identifier.hkuros | 21914 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0001195318&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 15 | en_US |
dc.identifier.issue | 11 | en_US |
dc.identifier.spage | 1853 | en_US |
dc.identifier.epage | 1858 | en_US |
dc.identifier.isi | WOS:A1996UA24400015 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Wang, CF=7501627178 | en_US |
dc.identifier.scopusauthorid | Peng, SM=35464852200 | en_US |
dc.identifier.scopusauthorid | Chan, CK=27167728200 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 0277-5387 | - |