File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/ic00252a019
- Scopus: eid_2-s2.0-0013550017
- WOS: WOS:A1987G372400019
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Monooxo complexes of ruthenium(V) as homogeneous redox catalysts for the electrooxidation of benzyl alcohol
| Title | Monooxo complexes of ruthenium(V) as homogeneous redox catalysts for the electrooxidation of benzyl alcohol |
|---|---|
| Authors | |
| Issue Date | 1987 |
| Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
| Citation | Inorganic Chemistry, 1987, v. 26 n. 5, p. 737-741 How to Cite? |
| Abstract | The electrochemical behavior of three Ru(IV)-monooxo complexes, trans-[RuIV(TMC)O(X)]ClO4 (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane; X- = Cl-, NCO-, N3 -), in acetonitrile is described. The formal potentials of the Ru(V)/Ru(IV) couples decrease in the order Cl- > NCO- > N3 -. The electrochemically generated Ru(V)-monooxo complexes are active catalysts for the oxidation of benzyl alcohol to benzaldehyde. The rate of benzyl alcohol oxidation decreases in the same order as the formal potentials. The second-order rate constants for reaction between the Ru(V) complexes and benzyl alcohol were evaluated by rotating disk voltammetry. The values obtained were 2.1 × 102 and 1.4 × 102 M-1 s-1 for X- = Cl- and NCO-, respectively. The catalysts gradually lose their activity during the course of the electrooxidation of benzyl alcohol because of what appears to be decomposition of the catalysts during the period that they are in the Ru(V) oxidation state. © 1987 American Chemical Society. |
| Persistent Identifier | http://hdl.handle.net/10722/167415 |
| ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Wong, KY | en_US |
| dc.contributor.author | Che, CM | en_US |
| dc.contributor.author | Anson, FC | en_US |
| dc.date.accessioned | 2012-10-08T03:06:41Z | - |
| dc.date.available | 2012-10-08T03:06:41Z | - |
| dc.date.issued | 1987 | en_US |
| dc.identifier.citation | Inorganic Chemistry, 1987, v. 26 n. 5, p. 737-741 | en_US |
| dc.identifier.issn | 0020-1669 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10722/167415 | - |
| dc.description.abstract | The electrochemical behavior of three Ru(IV)-monooxo complexes, trans-[RuIV(TMC)O(X)]ClO4 (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane; X- = Cl-, NCO-, N3 -), in acetonitrile is described. The formal potentials of the Ru(V)/Ru(IV) couples decrease in the order Cl- > NCO- > N3 -. The electrochemically generated Ru(V)-monooxo complexes are active catalysts for the oxidation of benzyl alcohol to benzaldehyde. The rate of benzyl alcohol oxidation decreases in the same order as the formal potentials. The second-order rate constants for reaction between the Ru(V) complexes and benzyl alcohol were evaluated by rotating disk voltammetry. The values obtained were 2.1 × 102 and 1.4 × 102 M-1 s-1 for X- = Cl- and NCO-, respectively. The catalysts gradually lose their activity during the course of the electrooxidation of benzyl alcohol because of what appears to be decomposition of the catalysts during the period that they are in the Ru(V) oxidation state. © 1987 American Chemical Society. | en_US |
| dc.language | eng | en_US |
| dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_US |
| dc.relation.ispartof | Inorganic Chemistry | en_US |
| dc.title | Monooxo complexes of ruthenium(V) as homogeneous redox catalysts for the electrooxidation of benzyl alcohol | en_US |
| dc.type | Article | en_US |
| dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
| dc.identifier.authority | Che, CM=rp00670 | en_US |
| dc.description.nature | link_to_subscribed_fulltext | en_US |
| dc.identifier.doi | 10.1021/ic00252a019 | - |
| dc.identifier.scopus | eid_2-s2.0-0013550017 | en_US |
| dc.identifier.volume | 26 | en_US |
| dc.identifier.issue | 5 | en_US |
| dc.identifier.spage | 737 | en_US |
| dc.identifier.epage | 741 | en_US |
| dc.identifier.isi | WOS:A1987G372400019 | - |
| dc.publisher.place | United States | en_US |
| dc.identifier.scopusauthorid | Wong, KY=7404760030 | en_US |
| dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
| dc.identifier.scopusauthorid | Anson, FC=7006393695 | en_US |
| dc.identifier.issnl | 0020-1669 | - |