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Article: Toward a potential total synthesis of gelsemine: A regioselective hydroboration directed by a remote olefin

TitleToward a potential total synthesis of gelsemine: A regioselective hydroboration directed by a remote olefin
Authors
Ng, FChiu, PDanishefsky, SJ
Issue Date1998
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet
Citation
Tetrahedron Letters, 1998, v. 39 n. 8, p. 767-770 How to Cite?
DOI: http://dx.doi.org/10.1016/S0040-4039(97)10621-9
AbstractHydroboration of bicyclo[3.2.1]octa-2,6-diene derivatives occurred exclusively on one olefin, and within this olefin, remarkable regioselective addition of boron to one carbon terminus was observed. This regioselectivity was significantly improved with more electrophilic hydroborating agents. The regioselectivity is attributed to the directive effect of a remote olefin.
Persistent Identifierhttp://hdl.handle.net/10722/167598
ISSN
0040-4039
2021 Impact Factor: 2.032
2020 SCImago Journal Rankings: 0.541
ISI Accession Number ID
WOS:000071788500012
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorNg, Fen_US
dc.contributor.authorChiu, Pen_US
dc.contributor.authorDanishefsky, SJen_US
dc.date.accessioned2012-10-08T03:08:55Z-
dc.date.available2012-10-08T03:08:55Z-
dc.date.issued1998en_US
dc.identifier.citationTetrahedron Letters, 1998, v. 39 n. 8, p. 767-770en_US
dc.identifier.issn0040-4039en_US
dc.identifier.urihttp://hdl.handle.net/10722/167598-
dc.description.abstractHydroboration of bicyclo[3.2.1]octa-2,6-diene derivatives occurred exclusively on one olefin, and within this olefin, remarkable regioselective addition of boron to one carbon terminus was observed. This regioselectivity was significantly improved with more electrophilic hydroborating agents. The regioselectivity is attributed to the directive effect of a remote olefin.en_US
dc.languageengen_US
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetleten_US
dc.relation.ispartofTetrahedron Lettersen_US
dc.titleToward a potential total synthesis of gelsemine: A regioselective hydroboration directed by a remote olefinen_US
dc.typeArticleen_US
dc.identifier.emailChiu, P:pchiu@hku.hken_US
dc.identifier.authorityChiu, P=rp00680en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0040-4039(97)10621-9en_US
dc.identifier.scopuseid_2-s2.0-0032546077en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0032546077&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume39en_US
dc.identifier.issue8en_US
dc.identifier.spage767en_US
dc.identifier.epage770en_US
dc.identifier.isiWOS:000071788500012-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridNg, F=7103125297en_US
dc.identifier.scopusauthoridChiu, P=11140148700en_US
dc.identifier.scopusauthoridDanishefsky, SJ=7202925243en_US
dc.identifier.issnl0040-4039-

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