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Article: The intrinsic 3[dσ*pσ] emission of binuclear gold(I) complexes with two bridging diphosphane ligands lies in the near UV; emissions in the visible region are due to exciplexes

TitleThe intrinsic 3[dσ*pσ] emission of binuclear gold(I) complexes with two bridging diphosphane ligands lies in the near UV; emissions in the visible region are due to exciplexes
Authors
Fu, WFChan, KCMiskowski, VMChe, CM
KeywordsBinuclear Complexes
Exciplexes
Gold
Luminescence
Uv/Vis Spectroscopy
Issue Date1999
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 1999, v. 38 n. 18, p. 2783-2785 How to Cite?
DOI: http://dx.doi.org/10.1002/(SICI)1521-3773(19990917)38:18<2783::AID-ANIE2783>3.0.CO;2-I
AbstractA near-UV triplet emission from [Au2(dcpm)2](ClO4)2 has been discovered. Studies on the spectroscopic properties of the complexes [Au2(dcpm)2]Y2 (Y=ClO4 -, PF6 -, CF3SO3 -, [Au(CN)2]-, Cl-, and I- ; dcpm = bis(dicyclohexylphosphanyl)methane) support the assignment of the high-energy emissions at 360-368 nm to the 3[dσ*pσ] excited state, adducts of which exhibit exciplex emissions in the visible region with solvent or counterions (see schematic diagram).
Persistent Identifierhttp://hdl.handle.net/10722/167629
ISSN
1433-7851
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID
WOS:000082853600027
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorFu, WFen_US
dc.contributor.authorChan, KCen_US
dc.contributor.authorMiskowski, VMen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:09:14Z-
dc.date.available2012-10-08T03:09:14Z-
dc.date.issued1999en_US
dc.identifier.citationAngewandte Chemie - International Edition, 1999, v. 38 n. 18, p. 2783-2785en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10722/167629-
dc.description.abstractA near-UV triplet emission from [Au2(dcpm)2](ClO4)2 has been discovered. Studies on the spectroscopic properties of the complexes [Au2(dcpm)2]Y2 (Y=ClO4 -, PF6 -, CF3SO3 -, [Au(CN)2]-, Cl-, and I- ; dcpm = bis(dicyclohexylphosphanyl)methane) support the assignment of the high-energy emissions at 360-368 nm to the 3[dσ*pσ] excited state, adducts of which exhibit exciplex emissions in the visible region with solvent or counterions (see schematic diagram).en_US
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_US
dc.relation.ispartofAngewandte Chemie - International Editionen_US
dc.subjectBinuclear Complexesen_US
dc.subjectExciplexesen_US
dc.subjectGolden_US
dc.subjectLuminescenceen_US
dc.subjectUv/Vis Spectroscopyen_US
dc.titleThe intrinsic 3[dσ*pσ] emission of binuclear gold(I) complexes with two bridging diphosphane ligands lies in the near UV; emissions in the visible region are due to exciplexesen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/(SICI)1521-3773(19990917)38:18<2783::AID-ANIE2783>3.0.CO;2-Ien_US
dc.identifier.scopuseid_2-s2.0-0033578796en_US
dc.identifier.hkuros54598-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0033578796&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume38en_US
dc.identifier.issue18en_US
dc.identifier.spage2783en_US
dc.identifier.epage2785en_US
dc.identifier.isiWOS:000082853600027-
dc.publisher.placeGermanyen_US
dc.identifier.scopusauthoridFu, WF=7202947315en_US
dc.identifier.scopusauthoridChan, KC=13609968400en_US
dc.identifier.scopusauthoridMiskowski, VM=6603008214en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.issnl1433-7851-

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