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- Publisher Website: 10.1002/1099-0682(200010)2000:10<2159::AID-EJIC2159>3.0.CO;2-2
- Scopus: eid_2-s2.0-0033770768
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Article: Synthesis and crystal structures of monomeric diamidonickel(II) complexes
Title | Synthesis and crystal structures of monomeric diamidonickel(II) complexes |
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Authors | |
Keywords | Amides Chelates Magnetic Properties N Ligands Nickel |
Issue Date | 2000 |
Publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.org |
Citation | European Journal Of Inorganic Chemistry, 2000 n. 10, p. 2159-2162 How to Cite? |
Abstract | The thermally stable nickel(II) diamides [NiL 2] [L = -N(SiMe 3)(8-C 9H 6N) (1), -N(SitBuMe 2)(8-C 9H 6N) (2)] have been synthesized from the reaction of NiCl 2 with the appropriate lithium amide. X-ray crystallography revealed that the amido ligands bind in a chelating manner, forming a distorted tetrahedral environment around the nickel center. Complexes 1 and 2 have magnetic moments of 3.05 and 2.74 μ(B), respectively, which indicate a d 8 electronic configuration with two unpaired electrons. |
Persistent Identifier | http://hdl.handle.net/10722/167640 |
ISSN | 2023 Impact Factor: 2.2 2023 SCImago Journal Rankings: 0.481 |
References |
DC Field | Value | Language |
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dc.contributor.author | Lee, HK | en_US |
dc.contributor.author | Yu, P | en_US |
dc.contributor.author | Kui, SCF | en_US |
dc.contributor.author | Zhang, ZY | en_US |
dc.contributor.author | Zhou, ZY | en_US |
dc.contributor.author | Mak, TCW | en_US |
dc.date.accessioned | 2012-10-08T03:09:22Z | - |
dc.date.available | 2012-10-08T03:09:22Z | - |
dc.date.issued | 2000 | en_US |
dc.identifier.citation | European Journal Of Inorganic Chemistry, 2000 n. 10, p. 2159-2162 | en_US |
dc.identifier.issn | 1434-1948 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167640 | - |
dc.description.abstract | The thermally stable nickel(II) diamides [NiL 2] [L = -N(SiMe 3)(8-C 9H 6N) (1), -N(SitBuMe 2)(8-C 9H 6N) (2)] have been synthesized from the reaction of NiCl 2 with the appropriate lithium amide. X-ray crystallography revealed that the amido ligands bind in a chelating manner, forming a distorted tetrahedral environment around the nickel center. Complexes 1 and 2 have magnetic moments of 3.05 and 2.74 μ(B), respectively, which indicate a d 8 electronic configuration with two unpaired electrons. | en_US |
dc.language | eng | en_US |
dc.publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.org | en_US |
dc.relation.ispartof | European Journal of Inorganic Chemistry | en_US |
dc.subject | Amides | en_US |
dc.subject | Chelates | en_US |
dc.subject | Magnetic Properties | en_US |
dc.subject | N Ligands | en_US |
dc.subject | Nickel | en_US |
dc.title | Synthesis and crystal structures of monomeric diamidonickel(II) complexes | en_US |
dc.type | Article | en_US |
dc.identifier.email | Kui, SCF:stevenku@hku.hk | en_US |
dc.identifier.authority | Kui, SCF=rp00715 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1002/1099-0682(200010)2000:10<2159::AID-EJIC2159>3.0.CO;2-2 | - |
dc.identifier.scopus | eid_2-s2.0-0033770768 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0033770768&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.issue | 10 | en_US |
dc.identifier.spage | 2159 | en_US |
dc.identifier.epage | 2162 | en_US |
dc.publisher.place | Germany | en_US |
dc.identifier.scopusauthorid | Lee, HK=7501482998 | en_US |
dc.identifier.scopusauthorid | Yu, P=55223089400 | en_US |
dc.identifier.scopusauthorid | Kui, SCF=6506763660 | en_US |
dc.identifier.scopusauthorid | Zhang, ZY=8141639100 | en_US |
dc.identifier.scopusauthorid | Zhou, ZY=7406096262 | en_US |
dc.identifier.scopusauthorid | Mak, TCW=7401931058 | en_US |
dc.identifier.issnl | 1434-1948 | - |