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Article: Transient resonance Raman investigation of CHBr2 and CHBrCl radicals

TitleTransient resonance Raman investigation of CHBr2 and CHBrCl radicals
Authors
Li, YAZuo, PPhillips, DL
Issue Date2002
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 2002, v. 364 n. 5-6, p. 573-579 How to Cite?
DOI: http://dx.doi.org/10.1016/S0009-2614(02)01403-3
AbstractTransient resonance Raman spectra of CHBr2 and CHBrCl radicals following ultraviolet photolysis of CHBr3 and CHBr2Cl, respectively, in methanol solution are reported. Most of the Raman intensity appears in the C-Br stretch and Br-C-Br bend or Cl-C-Br bend fundamentals accompanied by moderate intensity in their overtones and/or combination bands. The CH2Br radical was previously observed to have only one predominant Franck-Condon active mode (the C-Br stretch) with a strong overtone progression. The Franck-Condon region photodissociation dynamics of the CHBr2 and CHBrCl radicals appear to have more multidimensional character compared to halomethyl radicals like CH2Br. © 2002 Elsevier Science B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/167758
ISSN
0009-2614
2021 Impact Factor: 2.719
2020 SCImago Journal Rankings: 0.509
ISI Accession Number ID
WOS:000178630800023
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorLi, YAen_US
dc.contributor.authorZuo, Pen_US
dc.contributor.authorPhillips, DLen_US
dc.date.accessioned2012-10-08T03:11:05Z-
dc.date.available2012-10-08T03:11:05Z-
dc.date.issued2002en_US
dc.identifier.citationChemical Physics Letters, 2002, v. 364 n. 5-6, p. 573-579en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/167758-
dc.description.abstractTransient resonance Raman spectra of CHBr2 and CHBrCl radicals following ultraviolet photolysis of CHBr3 and CHBr2Cl, respectively, in methanol solution are reported. Most of the Raman intensity appears in the C-Br stretch and Br-C-Br bend or Cl-C-Br bend fundamentals accompanied by moderate intensity in their overtones and/or combination bands. The CH2Br radical was previously observed to have only one predominant Franck-Condon active mode (the C-Br stretch) with a strong overtone progression. The Franck-Condon region photodissociation dynamics of the CHBr2 and CHBrCl radicals appear to have more multidimensional character compared to halomethyl radicals like CH2Br. © 2002 Elsevier Science B.V. All rights reserved.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleTransient resonance Raman investigation of CHBr2 and CHBrCl radicalsen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0009-2614(02)01403-3en_US
dc.identifier.scopuseid_2-s2.0-0037120784en_US
dc.identifier.hkuros77160-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037120784&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume364en_US
dc.identifier.issue5-6en_US
dc.identifier.spage573en_US
dc.identifier.epage579en_US
dc.identifier.isiWOS:000178630800023-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridLi, YA=26643632900en_US
dc.identifier.scopusauthoridZuo, P=35068878800en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.issnl0009-2614-

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