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- Publisher Website: 10.1021/ic00206a019
- Scopus: eid_2-s2.0-0039847092
- WOS: WOS:A1985AJS2700019
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Article: A high-valent ruthenium(VI) dioxo cation of 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane
| Title | A high-valent ruthenium(VI) dioxo cation of 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane |
|---|---|
| Authors | |
| Issue Date | 1985 |
| Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
| Citation | Inorganic Chemistry, 1985, v. 24 n. 12, p. 1797-1800 How to Cite? |
| Abstract | A high-valent trans-[Ru(TMC)O2]2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) cation has been produced from trans-[Ru(TMC)Cl2]+ through H2O2 oxidation. This novel diamagnetic ruthenium(VI) dioxo species has been subjected to detailed spectroscopic and electrochemical characterization. The UV-vis absorption spectra of trans-[Ru(TMC)O2]2+ and the previously reported trans-[Ru(NH3)4O2]2+ exhibit a weak vibronic structured absorption band at ∼390 nm. Cyclic voltammetric and controlled-potential coulometric experiments showed that the reduction of trans-[Ru(TMC)O2]2+ to trans-[Ru(TMC)O-(H2O)]2+ proceeded by a single-step two-electron-transfer process. © 1985 American Chemical Society. |
| Persistent Identifier | http://hdl.handle.net/10722/167809 |
| ISSN | 2021 Impact Factor: 5.436 2020 SCImago Journal Rankings: 1.348 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Che, CM | en_US |
| dc.contributor.author | Wong, KY | en_US |
| dc.contributor.author | Poon, CK | en_US |
| dc.date.accessioned | 2012-10-08T03:11:53Z | - |
| dc.date.available | 2012-10-08T03:11:53Z | - |
| dc.date.issued | 1985 | en_US |
| dc.identifier.citation | Inorganic Chemistry, 1985, v. 24 n. 12, p. 1797-1800 | en_US |
| dc.identifier.issn | 0020-1669 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10722/167809 | - |
| dc.description.abstract | A high-valent trans-[Ru(TMC)O2]2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) cation has been produced from trans-[Ru(TMC)Cl2]+ through H2O2 oxidation. This novel diamagnetic ruthenium(VI) dioxo species has been subjected to detailed spectroscopic and electrochemical characterization. The UV-vis absorption spectra of trans-[Ru(TMC)O2]2+ and the previously reported trans-[Ru(NH3)4O2]2+ exhibit a weak vibronic structured absorption band at ∼390 nm. Cyclic voltammetric and controlled-potential coulometric experiments showed that the reduction of trans-[Ru(TMC)O2]2+ to trans-[Ru(TMC)O-(H2O)]2+ proceeded by a single-step two-electron-transfer process. © 1985 American Chemical Society. | en_US |
| dc.language | eng | en_US |
| dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_US |
| dc.relation.ispartof | Inorganic Chemistry | en_US |
| dc.title | A high-valent ruthenium(VI) dioxo cation of 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane | en_US |
| dc.type | Article | en_US |
| dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
| dc.identifier.authority | Che, CM=rp00670 | en_US |
| dc.description.nature | link_to_subscribed_fulltext | en_US |
| dc.identifier.doi | 10.1021/ic00206a019 | - |
| dc.identifier.scopus | eid_2-s2.0-0039847092 | en_US |
| dc.identifier.volume | 24 | en_US |
| dc.identifier.issue | 12 | en_US |
| dc.identifier.spage | 1797 | en_US |
| dc.identifier.epage | 1800 | en_US |
| dc.identifier.isi | WOS:A1985AJS2700019 | - |
| dc.publisher.place | United States | en_US |
| dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
| dc.identifier.scopusauthorid | Wong, KY=7404760030 | en_US |
| dc.identifier.scopusauthorid | Poon, CK=7202673504 | en_US |
| dc.identifier.issnl | 0020-1669 | - |