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Article: First observation of alkali metal ion induced trans-cis isomerization of palladium(II) phosphane complexes containing crown ether moieties

TitleFirst observation of alkali metal ion induced trans-cis isomerization of palladium(II) phosphane complexes containing crown ether moieties
Authors
Yam, VWWLu, XXKo, CC
KeywordsAlkali metals
Crown compounds
Host-guest systems
Isomerization
Palladium
Issue Date2003
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2003, v. 42 n. 29, p. 3385-3388 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.200351178
AbstractIon switches: The addition of small metal ions (such as Li+ and Na+) to transpalladium(II) complexes of PPh2-substituted benzo[15]crown-5 and benzo[18]-crown-6 results in the formation of 1:1 trans adducts. However, the addition of large alkali ions (such as K+, Rb+, and Cs+) enforces the complexes to undergo a trans-cis isomerization to enable formation of intramolecular sandwich adducts (see schematic representation).
Persistent Identifierhttp://hdl.handle.net/10722/167824
ISSN
1433-7851
2021 Impact Factor: 16.823
2020 SCImago Journal Rankings: 5.831
ISI Accession Number ID
WOS:000184548700011
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorLu, XXen_US
dc.contributor.authorKo, CCen_US
dc.date.accessioned2012-10-08T03:11:59Z-
dc.date.available2012-10-08T03:11:59Z-
dc.date.issued2003en_US
dc.identifier.citationAngewandte Chemie - International Edition, 2003, v. 42 n. 29, p. 3385-3388en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10722/167824-
dc.description.abstractIon switches: The addition of small metal ions (such as Li+ and Na+) to transpalladium(II) complexes of PPh2-substituted benzo[15]crown-5 and benzo[18]-crown-6 results in the formation of 1:1 trans adducts. However, the addition of large alkali ions (such as K+, Rb+, and Cs+) enforces the complexes to undergo a trans-cis isomerization to enable formation of intramolecular sandwich adducts (see schematic representation).en_US
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_US
dc.relation.ispartofAngewandte Chemie - International Editionen_US
dc.subjectAlkali metals-
dc.subjectCrown compounds-
dc.subjectHost-guest systems-
dc.subjectIsomerization-
dc.subjectPalladium-
dc.titleFirst observation of alkali metal ion induced trans-cis isomerization of palladium(II) phosphane complexes containing crown ether moietiesen_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/anie.200351178en_US
dc.identifier.pmid12888965-
dc.identifier.scopuseid_2-s2.0-0042530482en_US
dc.identifier.hkuros92790-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0042530482&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume42en_US
dc.identifier.issue29en_US
dc.identifier.spage3385en_US
dc.identifier.epage3388en_US
dc.identifier.isiWOS:000184548700011-
dc.publisher.placeGermanyen_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridLu, XX=7404839171en_US
dc.identifier.scopusauthoridKo, CC=7202596455en_US
dc.identifier.issnl1433-7851-

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