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Article: Characterization of a high-valent ruthenyl (RuIV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2

TitleCharacterization of a high-valent ruthenyl (RuIV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2
Authors
Che, CMWong, KYMak, TCW
Issue Date1985
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1985 n. 9, p. 546-548 How to Cite?
DOI: http://dx.doi.org/10.1039/C39850000546
Abstracttrans-[RuIV(tmc)O(MeCN)][PF6]2 (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3 with trans-[RuVI(tmc)O 2][PF6]2 in MeCN; the Ru=O distance in this mono-oxo ruthenium(IV) (ruthenyl) species, as determined by X-ray crystallography, is 1.765(5) Å.
Persistent Identifierhttp://hdl.handle.net/10722/167898
ISSN
0022-4936
ISI Accession Number ID
WOS:A1985AGK1700013

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorWong, KYen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:12:41Z-
dc.date.available2012-10-08T03:12:41Z-
dc.date.issued1985en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1985 n. 9, p. 546-548en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/167898-
dc.description.abstracttrans-[RuIV(tmc)O(MeCN)][PF6]2 (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3 with trans-[RuVI(tmc)O 2][PF6]2 in MeCN; the Ru=O distance in this mono-oxo ruthenium(IV) (ruthenyl) species, as determined by X-ray crystallography, is 1.765(5) Å.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleCharacterization of a high-valent ruthenyl (RuIV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39850000546-
dc.identifier.scopuseid_2-s2.0-1542355668en_US
dc.identifier.issue9en_US
dc.identifier.spage546en_US
dc.identifier.epage548en_US
dc.identifier.isiWOS:A1985AGK1700013-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridWong, KY=7404760030en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US
dc.identifier.issnl0022-4936-

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