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- Publisher Website: 10.1016/0010-8545(94)80027-8
- Scopus: eid_2-s2.0-1542724198
- WOS: WOS:A1994NM69200012
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Article: Luminescent donor-acceptor platinum(II) complexes
Title | Luminescent donor-acceptor platinum(II) complexes |
---|---|
Authors | |
Issue Date | 1994 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr |
Citation | Coordination Chemistry Reviews, 1994, v. 132, p. 87-97 How to Cite? |
Abstract | The emission properties of the complexes [Pt(dppm)(5,6-Me2phen)](ClO4)2, [Pt(phen)(C≡CPh)2], [Pt(5-Ph-phen)(CN)2] and [Pt(CNN-dpp)(NCCH3)](ClO4) have been studied. The large percentage of metal-ligand charge transfer character in the lowest excited states of these platinum(II) complexes has been demonstrated. Excited state oxidation and reduction potentials of [Pt(phen)(C≡CPh)2] have been determined. The 3MLCT excited state of Pt(II) is highly electrophilic as suggested by the large kinetic isotope effect (kH/kD = 6.7) observed in the quenching of the photoexcited [Pt(dppm)(5,6-Me2phen)](ClO4)2 complex by cyclohexene and d10-cyclohexene. Facile replacement of the coordinated acetonitrile in [Pt(CNN-dpp)(NCCH3)](ClO4) by pyridine ligands provides an entry to a new class of emissive donor-acceptor cyclometallated platinum(II) complexes. |
Persistent Identifier | http://hdl.handle.net/10722/167903 |
ISSN | 2023 Impact Factor: 20.3 2023 SCImago Journal Rankings: 4.145 |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chan, CW | en_US |
dc.contributor.author | Cheng, LK | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:12:44Z | - |
dc.date.available | 2012-10-08T03:12:44Z | - |
dc.date.issued | 1994 | en_US |
dc.identifier.citation | Coordination Chemistry Reviews, 1994, v. 132, p. 87-97 | en_US |
dc.identifier.issn | 0010-8545 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167903 | - |
dc.description.abstract | The emission properties of the complexes [Pt(dppm)(5,6-Me2phen)](ClO4)2, [Pt(phen)(C≡CPh)2], [Pt(5-Ph-phen)(CN)2] and [Pt(CNN-dpp)(NCCH3)](ClO4) have been studied. The large percentage of metal-ligand charge transfer character in the lowest excited states of these platinum(II) complexes has been demonstrated. Excited state oxidation and reduction potentials of [Pt(phen)(C≡CPh)2] have been determined. The 3MLCT excited state of Pt(II) is highly electrophilic as suggested by the large kinetic isotope effect (kH/kD = 6.7) observed in the quenching of the photoexcited [Pt(dppm)(5,6-Me2phen)](ClO4)2 complex by cyclohexene and d10-cyclohexene. Facile replacement of the coordinated acetonitrile in [Pt(CNN-dpp)(NCCH3)](ClO4) by pyridine ligands provides an entry to a new class of emissive donor-acceptor cyclometallated platinum(II) complexes. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr | en_US |
dc.relation.ispartof | Coordination Chemistry Reviews | en_US |
dc.title | Luminescent donor-acceptor platinum(II) complexes | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/0010-8545(94)80027-8 | - |
dc.identifier.scopus | eid_2-s2.0-1542724198 | en_US |
dc.identifier.volume | 132 | en_US |
dc.identifier.spage | 87 | en_US |
dc.identifier.epage | 97 | en_US |
dc.identifier.isi | WOS:A1994NM69200012 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Chan, CW=7404814723 | en_US |
dc.identifier.scopusauthorid | Cheng, LK=7403337077 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 0010-8545 | - |