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Article: Unexpected reactivities of Cu2(diphosphine)2 complexes in alcohol: Isolation, X-ray crystal structure, and photoluminescent properties of a remarkably stable [Cu3(diphosphine) 3(μ3-H)]2+ hydride complex

TitleUnexpected reactivities of Cu2(diphosphine)2 complexes in alcohol: Isolation, X-ray crystal structure, and photoluminescent properties of a remarkably stable [Cu3(diphosphine) 3(μ3-H)]2+ hydride complex
Authors
Mao, ZHuang, JSChe, CMZhu, NLeung, SKYZhou, ZY
Issue Date2005
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 2005, v. 127 n. 13, p. 4562-4563 How to Cite?
DOI: http://dx.doi.org/10.1021/ja042335c
AbstractTreatment of [Cu2(dcpm)2]Y2 (dcpm = bis(dicyclohexylphosphino)methane, Y = ClO4 -, BF4 -, PF6 -, CF3SO3 -) with refluxing MeOH in the presence of KOH afforded hydride complexes [Cu3(dcpm)3(μ3-H)]Y2 (1) in about 85% yield. Refluxing [Cu2(dcpm)2](PF6)2 with MeOH in the presence of NH3·H2O and air gave a carboxylate complex [Cu2(dcpm)2(O2CCH2OH)]PF6 (2) in 40% yield. All of the complexes 1 and 2 have been characterized by X-ray crystallography. The Cu3 cores in 1 are almost perfectly shielded by the dcpm ligands. Intense photoluminescence was observed for 1 both in the solid state and in solution. Copyright © 2005 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167911
ISSN
0002-7863
2021 Impact Factor: 16.383
2020 SCImago Journal Rankings: 7.115
ISI Accession Number ID
WOS:000228089300010
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorMao, Zen_HK
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorLeung, SKYen_HK
dc.contributor.authorZhou, ZYen_HK
dc.date.accessioned2012-10-08T03:12:50Z-
dc.date.available2012-10-08T03:12:50Z-
dc.date.issued2005en_HK
dc.identifier.citationJournal Of The American Chemical Society, 2005, v. 127 n. 13, p. 4562-4563en_HK
dc.identifier.issn0002-7863en_HK
dc.identifier.urihttp://hdl.handle.net/10722/167911-
dc.description.abstractTreatment of [Cu2(dcpm)2]Y2 (dcpm = bis(dicyclohexylphosphino)methane, Y = ClO4 -, BF4 -, PF6 -, CF3SO3 -) with refluxing MeOH in the presence of KOH afforded hydride complexes [Cu3(dcpm)3(μ3-H)]Y2 (1) in about 85% yield. Refluxing [Cu2(dcpm)2](PF6)2 with MeOH in the presence of NH3·H2O and air gave a carboxylate complex [Cu2(dcpm)2(O2CCH2OH)]PF6 (2) in 40% yield. All of the complexes 1 and 2 have been characterized by X-ray crystallography. The Cu3 cores in 1 are almost perfectly shielded by the dcpm ligands. Intense photoluminescence was observed for 1 both in the solid state and in solution. Copyright © 2005 American Chemical Society.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_HK
dc.relation.ispartofJournal of the American Chemical Societyen_HK
dc.titleUnexpected reactivities of Cu2(diphosphine)2 complexes in alcohol: Isolation, X-ray crystal structure, and photoluminescent properties of a remarkably stable [Cu3(diphosphine) 3(μ3-H)]2+ hydride complexen_HK
dc.typeArticleen_HK
dc.identifier.emailHuang, JS: jshuang@hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ja042335cen_HK
dc.identifier.pmid15796507-
dc.identifier.scopuseid_2-s2.0-16844379423en_HK
dc.identifier.hkuros98442-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-16844379423&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume127en_HK
dc.identifier.issue13en_HK
dc.identifier.spage4562en_HK
dc.identifier.epage4563en_HK
dc.identifier.isiWOS:000228089300010-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridMao, Z=7202633924en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridLeung, SKY=36546285500en_HK
dc.identifier.scopusauthoridZhou, ZY=7406096262en_HK
dc.identifier.citeulike4364126-
dc.identifier.issnl0002-7863-

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