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Article: Novel epoxidation reaction of olefins using the combination of Chloramine-M, benzaldehyde, and BTEAC

TitleNovel epoxidation reaction of olefins using the combination of Chloramine-M, benzaldehyde, and BTEAC
Authors
Zhang, CYang, DWang, XC
Issue Date1999
PublisherAmerican Chemical Society. The Journal's web site is located at http://www.chemistry.org/portal/a/c/s/1/acsdisplay.html?DOC=meetingspast.html
Citation
Acs National Meeting Book Of Abstracts, 1999, v. PART 2, p. ORGN-522 How to Cite?
AbstractThe combination of Chloramine-M (CH3SO2NClNa), benzaldehyde and BTEAC epoxidized olefins with good yield. While the novel reaction was electrophilic, epoxidation of cis-olefins such as cis-β-methylstyrene, cis-stilbene, and 4-cis-octene yielded trans-epoxides as major products. Several experiments were performed to study the reaction mechanism. Cis-N-sulfonyl-oxaziridine A was suggested as a reactive intermediate in this epoxidation reaction.
Persistent Identifierhttp://hdl.handle.net/10722/167923
ISSN
0065-7727

 

DC FieldValueLanguage
dc.contributor.authorZhang, Cen_US
dc.contributor.authorYang, Den_US
dc.contributor.authorWang, XCen_US
dc.date.accessioned2012-10-08T03:12:59Z-
dc.date.available2012-10-08T03:12:59Z-
dc.date.issued1999en_US
dc.identifier.citationAcs National Meeting Book Of Abstracts, 1999, v. PART 2, p. ORGN-522en_US
dc.identifier.issn0065-7727en_US
dc.identifier.urihttp://hdl.handle.net/10722/167923-
dc.description.abstractThe combination of Chloramine-M (CH3SO2NClNa), benzaldehyde and BTEAC epoxidized olefins with good yield. While the novel reaction was electrophilic, epoxidation of cis-olefins such as cis-β-methylstyrene, cis-stilbene, and 4-cis-octene yielded trans-epoxides as major products. Several experiments were performed to study the reaction mechanism. Cis-N-sulfonyl-oxaziridine A was suggested as a reactive intermediate in this epoxidation reaction.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://www.chemistry.org/portal/a/c/s/1/acsdisplay.html?DOC=meetingspast.htmlen_US
dc.relation.ispartofACS National Meeting Book of Abstractsen_US
dc.titleNovel epoxidation reaction of olefins using the combination of Chloramine-M, benzaldehyde, and BTEACen_US
dc.typeArticleen_US
dc.identifier.emailYang, D:yangdan@hku.hken_US
dc.identifier.authorityYang, D=rp00825en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-18744427817en_US
dc.identifier.volumePART 2en_US
dc.identifier.spageORGNen_US
dc.identifier.epage522en_US
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridZhang, C=7405494641en_US
dc.identifier.scopusauthoridYang, D=7404800756en_US
dc.identifier.scopusauthoridWang, XC=9744761800en_US
dc.identifier.issnl0065-7727-

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