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- Publisher Website: 10.1021/ic0484102
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- PMID: 15907102
- WOS: WOS:000229381600005
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Article: Tuning the reactivity of dioxoruthenium(VI) porphyrins toward an arylimine by altering porphyrin substituants
Title | Tuning the reactivity of dioxoruthenium(VI) porphyrins toward an arylimine by altering porphyrin substituants |
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Authors | |
Issue Date | 2005 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
Citation | Inorganic Chemistry, 2005, v. 44 n. 11, p. 3780-3788 How to Cite? |
Abstract | Reaction of dioxoruthenium(VI) porphyrins [RuVI(Por)O 2] with arylimine HN=CPh2 in dichloromethane afforded bis-(methyleneamido)ruthenium(IV) porphyrins [RuIV(Por)(N=CPh 2)2] for Por = 4-CI-TPP and TMP; (methyleneamido)- hydroxoruthenium(IV) porphyrins [RuVI(Por)(N=CPh2)(OH)] for Por = TPP and TIP; and bis(arylimine)ruthenium(II) porphyrins [Ru II(Por)(HN=CPh2)2] for Por = 3,5-Cl 2TPP and 3,5-(CF3)2TPP. In dichloromethane solution exposed to air, complex [RuII(3,5-Cl2TPP)(HN= CPh2)2] underwent oxidative deprotonation.to form [Ru IV(3,5-Cl2TPP)(N= CPh2)2]. The new ruthenium porphyrins were identified by 1H NMR, UV-vis, IR, and mass spectroscopy, along with elemental analysis. X-ray crystal structure determinations of [RuIV(4-Cl-TPP)(N=CPh2)2], [RuIV(TPP)(N=CPh2)-(OH)], and [RuII(3,5- (CF3)2TPP)(HN=CPh2)2] revealed the Ru-N(methyleneamido) or Ru-N(arylimine) distances of 1.897(5) Å (average), 1.808(4) Å, and 2.044(2) Å (average), respectively. © 2005 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/167931 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Huang, JS | en_HK |
dc.contributor.author | Leung, SKY | en_HK |
dc.contributor.author | Zhou, ZY | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2012-10-08T03:13:04Z | - |
dc.date.available | 2012-10-08T03:13:04Z | - |
dc.date.issued | 2005 | en_HK |
dc.identifier.citation | Inorganic Chemistry, 2005, v. 44 n. 11, p. 3780-3788 | en_HK |
dc.identifier.issn | 0020-1669 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/167931 | - |
dc.description.abstract | Reaction of dioxoruthenium(VI) porphyrins [RuVI(Por)O 2] with arylimine HN=CPh2 in dichloromethane afforded bis-(methyleneamido)ruthenium(IV) porphyrins [RuIV(Por)(N=CPh 2)2] for Por = 4-CI-TPP and TMP; (methyleneamido)- hydroxoruthenium(IV) porphyrins [RuVI(Por)(N=CPh2)(OH)] for Por = TPP and TIP; and bis(arylimine)ruthenium(II) porphyrins [Ru II(Por)(HN=CPh2)2] for Por = 3,5-Cl 2TPP and 3,5-(CF3)2TPP. In dichloromethane solution exposed to air, complex [RuII(3,5-Cl2TPP)(HN= CPh2)2] underwent oxidative deprotonation.to form [Ru IV(3,5-Cl2TPP)(N= CPh2)2]. The new ruthenium porphyrins were identified by 1H NMR, UV-vis, IR, and mass spectroscopy, along with elemental analysis. X-ray crystal structure determinations of [RuIV(4-Cl-TPP)(N=CPh2)2], [RuIV(TPP)(N=CPh2)-(OH)], and [RuII(3,5- (CF3)2TPP)(HN=CPh2)2] revealed the Ru-N(methyleneamido) or Ru-N(arylimine) distances of 1.897(5) Å (average), 1.808(4) Å, and 2.044(2) Å (average), respectively. © 2005 American Chemical Society. | en_HK |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_HK |
dc.relation.ispartof | Inorganic Chemistry | en_HK |
dc.title | Tuning the reactivity of dioxoruthenium(VI) porphyrins toward an arylimine by altering porphyrin substituants | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Huang, JS: jshuang@hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.authority | Huang, JS=rp00709 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/ic0484102 | en_HK |
dc.identifier.pmid | 15907102 | - |
dc.identifier.scopus | eid_2-s2.0-20444461694 | en_HK |
dc.identifier.hkuros | 103780 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-20444461694&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 44 | en_HK |
dc.identifier.issue | 11 | en_HK |
dc.identifier.spage | 3780 | en_HK |
dc.identifier.epage | 3788 | en_HK |
dc.identifier.isi | WOS:000229381600005 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Huang, JS=7407192639 | en_HK |
dc.identifier.scopusauthorid | Leung, SKY=36546285500 | en_HK |
dc.identifier.scopusauthorid | Zhou, ZY=7406096262 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 0020-1669 | - |