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- Publisher Website: 10.1021/la050282m
- Scopus: eid_2-s2.0-20744450955
- PMID: 15924444
- WOS: WOS:000229717900004
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Article: Morphology of rhenium complex-containing polystyrene-block-poly(4- vinylpyridine) and its use as self-assembly templates for nanoparticles
Title | Morphology of rhenium complex-containing polystyrene-block-poly(4- vinylpyridine) and its use as self-assembly templates for nanoparticles |
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Authors | |
Issue Date | 2005 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/langmuir |
Citation | Langmuir, 2005, v. 21 n. 12, p. 5247-5250 How to Cite? |
Abstract | Polystyrene-block-poly(4-vinylpyridine) was functionalized with a chlorotricarbonyl rhenium(I) diimine complex. Compared to the metal-free copolymer, the copolymer-metal complex exhibited different morphologies, which are highly sensitive to the solvent used for spin-coating and the surface properties of the substrates. Well-defined cylindrical or spherical domains were observed. Due to its ionic nature, the poly(4-vinylpyridine)-rhenium complex block could also serve as a template for subsequent deposition of cadmium sulfide nanoparticles by electrostatic attraction. The pattern of the deposited nanoparticles was found to be the replica of the block copolymer underneath, and their presence on the film surface was confirmed by X-ray photoelectron spectroscopy. © 2005 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/167935 |
ISSN | 2023 Impact Factor: 3.7 2023 SCImago Journal Rankings: 0.786 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cheng, KW | en_US |
dc.contributor.author | Chan, WK | en_US |
dc.date.accessioned | 2012-10-08T03:13:07Z | - |
dc.date.available | 2012-10-08T03:13:07Z | - |
dc.date.issued | 2005 | en_US |
dc.identifier.citation | Langmuir, 2005, v. 21 n. 12, p. 5247-5250 | en_US |
dc.identifier.issn | 0743-7463 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167935 | - |
dc.description.abstract | Polystyrene-block-poly(4-vinylpyridine) was functionalized with a chlorotricarbonyl rhenium(I) diimine complex. Compared to the metal-free copolymer, the copolymer-metal complex exhibited different morphologies, which are highly sensitive to the solvent used for spin-coating and the surface properties of the substrates. Well-defined cylindrical or spherical domains were observed. Due to its ionic nature, the poly(4-vinylpyridine)-rhenium complex block could also serve as a template for subsequent deposition of cadmium sulfide nanoparticles by electrostatic attraction. The pattern of the deposited nanoparticles was found to be the replica of the block copolymer underneath, and their presence on the film surface was confirmed by X-ray photoelectron spectroscopy. © 2005 American Chemical Society. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/langmuir | en_US |
dc.relation.ispartof | Langmuir | en_US |
dc.subject.mesh | Macromolecular Substances - Chemistry | en_US |
dc.subject.mesh | Nanostructures - Chemistry | en_US |
dc.subject.mesh | Organometallic Compounds - Chemistry | en_US |
dc.subject.mesh | Polystyrenes - Chemistry | en_US |
dc.subject.mesh | Polyvinyls - Chemistry | en_US |
dc.subject.mesh | Pyridines - Chemistry | en_US |
dc.subject.mesh | Rhenium - Chemistry | en_US |
dc.title | Morphology of rhenium complex-containing polystyrene-block-poly(4- vinylpyridine) and its use as self-assembly templates for nanoparticles | en_US |
dc.type | Article | en_US |
dc.identifier.email | Chan, WK:waichan@hku.hk | en_US |
dc.identifier.authority | Chan, WK=rp00667 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/la050282m | en_US |
dc.identifier.pmid | 15924444 | - |
dc.identifier.scopus | eid_2-s2.0-20744450955 | en_US |
dc.identifier.hkuros | 100814 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-20744450955&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 21 | en_US |
dc.identifier.issue | 12 | en_US |
dc.identifier.spage | 5247 | en_US |
dc.identifier.epage | 5250 | en_US |
dc.identifier.isi | WOS:000229717900004 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Cheng, KW=36439221300 | en_US |
dc.identifier.scopusauthorid | Chan, WK=13310083000 | en_US |
dc.identifier.issnl | 0743-7463 | - |