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- Publisher Website: 10.1039/b516594f
- Scopus: eid_2-s2.0-33644771345
- PMID: 16518504
- WOS: WOS:000236280100012
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Article: Synthesis and reactivity of cobalt boryl complexes
Title | Synthesis and reactivity of cobalt boryl complexes |
---|---|
Authors | |
Issue Date | 2006 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
Citation | Dalton Transactions, 2006, v. 6 n. 11, p. 1370-1373 How to Cite? |
Abstract | The synthesis and reactivity of phosphine-cobalt boryls, were investigated. The reactivity studies have shown that alkyne diboration takes place and borylation of aryl bromides is possible with low selectivity. Boryl transfer was investigated initially by carrying out reactions between equimolar amounts of B2(cat)2, [Co (PMe3)4] and a 4-substituted aryl bromide in THF at room temperature. The results show that paramagnetic Co (II) bisboryls can be formed from Co (0) precursors and diborane (4) compounds. |
Persistent Identifier | http://hdl.handle.net/10722/168008 |
ISSN | 2021 Impact Factor: 4.569 2020 SCImago Journal Rankings: 0.980 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Adams, CJ | en_US |
dc.contributor.author | Baber, RA | en_US |
dc.contributor.author | Batsanov, AS | en_US |
dc.contributor.author | Bramham, G | en_US |
dc.contributor.author | Charmant, JPH | en_US |
dc.contributor.author | Haddow, MF | en_US |
dc.contributor.author | Howard, JAK | en_US |
dc.contributor.author | Lam, WH | en_US |
dc.contributor.author | Lin, Z | en_US |
dc.contributor.author | Marder, TB | en_US |
dc.contributor.author | Norman, NC | en_US |
dc.contributor.author | Orpen, AG | en_US |
dc.date.accessioned | 2012-10-08T03:14:03Z | - |
dc.date.available | 2012-10-08T03:14:03Z | - |
dc.date.issued | 2006 | en_US |
dc.identifier.citation | Dalton Transactions, 2006, v. 6 n. 11, p. 1370-1373 | en_US |
dc.identifier.issn | 1477-9226 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168008 | - |
dc.description.abstract | The synthesis and reactivity of phosphine-cobalt boryls, were investigated. The reactivity studies have shown that alkyne diboration takes place and borylation of aryl bromides is possible with low selectivity. Boryl transfer was investigated initially by carrying out reactions between equimolar amounts of B2(cat)2, [Co (PMe3)4] and a 4-substituted aryl bromide in THF at room temperature. The results show that paramagnetic Co (II) bisboryls can be formed from Co (0) precursors and diborane (4) compounds. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_US |
dc.relation.ispartof | Dalton Transactions | en_US |
dc.title | Synthesis and reactivity of cobalt boryl complexes | en_US |
dc.type | Article | en_US |
dc.identifier.email | Lam, WH:chsue@hku.hk | en_US |
dc.identifier.authority | Lam, WH=rp00719 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/b516594f | en_US |
dc.identifier.pmid | 16518504 | - |
dc.identifier.scopus | eid_2-s2.0-33644771345 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33644771345&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 6 | en_US |
dc.identifier.issue | 11 | en_US |
dc.identifier.spage | 1370 | en_US |
dc.identifier.epage | 1373 | en_US |
dc.identifier.isi | WOS:000236280100012 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Adams, CJ=7402375848 | en_US |
dc.identifier.scopusauthorid | Baber, RA=8235380500 | en_US |
dc.identifier.scopusauthorid | Batsanov, AS=35448086200 | en_US |
dc.identifier.scopusauthorid | Bramham, G=12767045800 | en_US |
dc.identifier.scopusauthorid | Charmant, JPH=7004139923 | en_US |
dc.identifier.scopusauthorid | Haddow, MF=8948446800 | en_US |
dc.identifier.scopusauthorid | Howard, JAK=35444331700 | en_US |
dc.identifier.scopusauthorid | Lam, WH=26642862800 | en_US |
dc.identifier.scopusauthorid | Lin, Z=7404230177 | en_US |
dc.identifier.scopusauthorid | Marder, TB=7006433068 | en_US |
dc.identifier.scopusauthorid | Norman, NC=7005094633 | en_US |
dc.identifier.scopusauthorid | Orpen, AG=7004717067 | en_US |
dc.identifier.issnl | 1477-9226 | - |