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- Scopus: eid_2-s2.0-33746901632
- PMID: 16841971
- WOS: WOS:000239040000005
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Article: One-pot synthesis of metal primary phosphine complexes from O=PCl 2R or PCl 2R. Isolation and characterization of primary alkylphosphine complexes of a metalloporphyrin
Title | One-pot synthesis of metal primary phosphine complexes from O=PCl 2R or PCl 2R. Isolation and characterization of primary alkylphosphine complexes of a metalloporphyrin |
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Authors | |
Issue Date | 2006 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
Citation | Inorganic Chemistry, 2006, v. 45 n. 15, p. 5724-5726 How to Cite? |
Abstract | Treatment of [Ru II(Por)(CO)] [Por = porphyrinato(2-)] and O=PCl 2R [R = Ad (adamantyl), Bu t, Bu sec] or PCl 2Mes (Mes = mesityl) with LiAlH 4 afforded primary alkyl- and arylphosphine complexes [Ru II(Por)(PH 2R) 2], which have been isolated in pure form and characterized by 1H NMR, 31P NMR, IR, and UV-vis spectroscopy and mass spectrometry. The structures of [Ru II(TTP)(PH 2Ad) 2] and [Ru II(F 20-TPP)(PH 2Mes) 2] were determined by X-ray crystallography. © 2006 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/168034 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Huang, JS | en_HK |
dc.contributor.author | Yu, GA | en_HK |
dc.contributor.author | Xie, J | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2012-10-08T03:14:23Z | - |
dc.date.available | 2012-10-08T03:14:23Z | - |
dc.date.issued | 2006 | en_HK |
dc.identifier.citation | Inorganic Chemistry, 2006, v. 45 n. 15, p. 5724-5726 | en_HK |
dc.identifier.issn | 0020-1669 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/168034 | - |
dc.description.abstract | Treatment of [Ru II(Por)(CO)] [Por = porphyrinato(2-)] and O=PCl 2R [R = Ad (adamantyl), Bu t, Bu sec] or PCl 2Mes (Mes = mesityl) with LiAlH 4 afforded primary alkyl- and arylphosphine complexes [Ru II(Por)(PH 2R) 2], which have been isolated in pure form and characterized by 1H NMR, 31P NMR, IR, and UV-vis spectroscopy and mass spectrometry. The structures of [Ru II(TTP)(PH 2Ad) 2] and [Ru II(F 20-TPP)(PH 2Mes) 2] were determined by X-ray crystallography. © 2006 American Chemical Society. | en_HK |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_HK |
dc.relation.ispartof | Inorganic Chemistry | en_HK |
dc.subject.mesh | Chlorine - Chemistry | en_US |
dc.subject.mesh | Crystallization | en_US |
dc.subject.mesh | Crystallography, X-Ray | en_US |
dc.subject.mesh | Ligands | en_US |
dc.subject.mesh | Magnetic Resonance Spectroscopy | en_US |
dc.subject.mesh | Mass Spectrometry | en_US |
dc.subject.mesh | Metalloporphyrins - Chemistry | en_US |
dc.subject.mesh | Metals - Chemistry | en_US |
dc.subject.mesh | Models, Chemical | en_US |
dc.subject.mesh | Models, Molecular | en_US |
dc.subject.mesh | Oxygen - Chemistry | en_US |
dc.subject.mesh | Phosphines - Chemical Synthesis - Chemistry | en_US |
dc.subject.mesh | Protons | en_US |
dc.subject.mesh | Spectrophotometry, Infrared - Methods | en_US |
dc.subject.mesh | Spectrophotometry, Ultraviolet | en_US |
dc.title | One-pot synthesis of metal primary phosphine complexes from O=PCl 2R or PCl 2R. Isolation and characterization of primary alkylphosphine complexes of a metalloporphyrin | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Huang, JS: jshuang@hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.authority | Huang, JS=rp00709 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/ic060553w | en_HK |
dc.identifier.pmid | 16841971 | - |
dc.identifier.scopus | eid_2-s2.0-33746901632 | en_HK |
dc.identifier.hkuros | 133100 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33746901632&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 45 | en_HK |
dc.identifier.issue | 15 | en_HK |
dc.identifier.spage | 5724 | en_HK |
dc.identifier.epage | 5726 | en_HK |
dc.identifier.eissn | 1520-510X | - |
dc.identifier.isi | WOS:000239040000005 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Huang, JS=7407192639 | en_HK |
dc.identifier.scopusauthorid | Yu, GA=8252045600 | en_HK |
dc.identifier.scopusauthorid | Xie, J=55478195600 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 0020-1669 | - |