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Article: Synthesis and photophysics of dinuclear gold(I) thiolates of bis(diphenylphosphino)-alkyl- and -aryl-amines. Crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2]

TitleSynthesis and photophysics of dinuclear gold(I) thiolates of bis(diphenylphosphino)-alkyl- and -aryl-amines. Crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2]
Authors
Yam, VWWChan, CLCheung, KK
Issue Date1996
Citation
Journal Of The Chemical Society - Dalton Transactions, 1996 n. 20, p. 4019-4022 How to Cite?
DOI: http://dx.doi.org/10.1039/DT9960004019
AbstractA series of luminescent dinuclear gold(I) thiolates, [Au2{Ph2PN(R)PPh2}(SR′)2] (R = C6H11, R′ = C6H4F-p, C6H4Cl-p, C6H4Me-p; R = Ph, R′ = C6H4Me-p; R = Prn, R′ = C6H4Me-p; R = Pri, R′ = C6H4Me-p) have been synthesized and their photophysical properties studied. The crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2] has been determined. These complexes have been shown to exhibit low-energy emission at ca. 600 nm, attributed to a ligand-to-metal charge transfer (thiolate to AuI) origin.
Persistent Identifierhttp://hdl.handle.net/10722/168045
ISSN
0300-9246
ISI Accession Number ID
WOS:A1996VR24800018
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorChan, CLen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:14:30Z-
dc.date.available2012-10-08T03:14:30Z-
dc.date.issued1996en_US
dc.identifier.citationJournal Of The Chemical Society - Dalton Transactions, 1996 n. 20, p. 4019-4022en_US
dc.identifier.issn0300-9246en_US
dc.identifier.urihttp://hdl.handle.net/10722/168045-
dc.description.abstractA series of luminescent dinuclear gold(I) thiolates, [Au2{Ph2PN(R)PPh2}(SR′)2] (R = C6H11, R′ = C6H4F-p, C6H4Cl-p, C6H4Me-p; R = Ph, R′ = C6H4Me-p; R = Prn, R′ = C6H4Me-p; R = Pri, R′ = C6H4Me-p) have been synthesized and their photophysical properties studied. The crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2] has been determined. These complexes have been shown to exhibit low-energy emission at ca. 600 nm, attributed to a ligand-to-metal charge transfer (thiolate to AuI) origin.en_US
dc.languageengen_US
dc.relation.ispartofJournal of the Chemical Society - Dalton Transactionsen_US
dc.titleSynthesis and photophysics of dinuclear gold(I) thiolates of bis(diphenylphosphino)-alkyl- and -aryl-amines. Crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2]en_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9960004019-
dc.identifier.scopuseid_2-s2.0-33748646998en_US
dc.identifier.hkuros21666-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33748646998&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue20en_US
dc.identifier.spage4019en_US
dc.identifier.epage4022en_US
dc.identifier.isiWOS:A1996VR24800018-
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridChan, CL=7404813631en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.issnl0300-9246-

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