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- Publisher Website: 10.1039/A705431I
- Scopus: eid_2-s2.0-33749113214
- WOS: WOS:A1997YB26400004
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Article: A novel luminescent iridium(I)-cadmium(II) binuclear complex displaying a long-lived metal-to-ligand charge-transfer excited state. Synthesis and structural characterisation of I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine]
Title | A novel luminescent iridium(I)-cadmium(II) binuclear complex displaying a long-lived metal-to-ligand charge-transfer excited state. Synthesis and structural characterisation of I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine] |
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Authors | |
Issue Date | 1997 |
Citation | Journal Of The Chemical Society - Dalton Transactions, 1997 n. 19, p. 3409-3410 How to Cite? |
Abstract | The first binuclear IrI-CdII complex to be structurally characterised, I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine], has a donor-acceptor metal-metal bond of length 2.784(1) Å; at room temperature, excitation of a solid sample of the complex with UV light led to a red emission at 739 nm with a lifetime of 6.48 μs that presumably originates from a 3MLCT excited state. |
Persistent Identifier | http://hdl.handle.net/10722/168054 |
ISSN | |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Kuang, SM | en_US |
dc.contributor.author | Xue, F | en_US |
dc.contributor.author | Zhang, ZZ | en_US |
dc.contributor.author | Xue, WM | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Mak, TCW | en_US |
dc.date.accessioned | 2012-10-08T03:14:36Z | - |
dc.date.available | 2012-10-08T03:14:36Z | - |
dc.date.issued | 1997 | en_US |
dc.identifier.citation | Journal Of The Chemical Society - Dalton Transactions, 1997 n. 19, p. 3409-3410 | en_US |
dc.identifier.issn | 0300-9246 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168054 | - |
dc.description.abstract | The first binuclear IrI-CdII complex to be structurally characterised, I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine], has a donor-acceptor metal-metal bond of length 2.784(1) Å; at room temperature, excitation of a solid sample of the complex with UV light led to a red emission at 739 nm with a lifetime of 6.48 μs that presumably originates from a 3MLCT excited state. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Journal of the Chemical Society - Dalton Transactions | en_US |
dc.title | A novel luminescent iridium(I)-cadmium(II) binuclear complex displaying a long-lived metal-to-ligand charge-transfer excited state. Synthesis and structural characterisation of I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine] | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/A705431I | - |
dc.identifier.scopus | eid_2-s2.0-33749113214 | en_US |
dc.identifier.hkuros | 32010 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33749113214&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.issue | 19 | en_US |
dc.identifier.spage | 3409 | en_US |
dc.identifier.epage | 3410 | en_US |
dc.identifier.isi | WOS:A1997YB26400004 | - |
dc.identifier.scopusauthorid | Kuang, SM=7006330379 | en_US |
dc.identifier.scopusauthorid | Xue, F=15052685300 | en_US |
dc.identifier.scopusauthorid | Zhang, ZZ=13405280100 | en_US |
dc.identifier.scopusauthorid | Xue, WM=7103165059 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Mak, TCW=35230525700 | en_US |
dc.identifier.issnl | 0300-9246 | - |