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Article: Metal-oxo photo-oxidants. Photochemistry and photophysics of trans-[Os VI(tmc)(O)2]2+ (tmc = 1,4,8,11-tetramethyl-1,4, 8,11-tetra-azacyclotetradecane) and trans-[OsVI(CN) 4(O)2]2-

TitleMetal-oxo photo-oxidants. Photochemistry and photophysics of trans-[Os VI(tmc)(O)2]2+ (tmc = 1,4,8,11-tetramethyl-1,4, 8,11-tetra-azacyclotetradecane) and trans-[OsVI(CN) 4(O)2]2-
Authors
Che, CMYam, VWWCho, KCGray, HB
Issue Date1987
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1987 n. 12, p. 948-949 How to Cite?
DOI: http://dx.doi.org/10.1039/C39870000948
Abstracttrans-[OsVI(tmc)(O)2]2+ (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) and trans-[Os VI(CN)4(O)2]2- are emissive in the solid state and in fluid solutions at room temperature (τ ∼ 1.0-1.5 μs); the 3Eg state of trans-[OsVI(tmc)(O) 2]2+ is a powerful one-electron oxidant {[Os VI(O)2]2+ + e- → [Os V(O)2]+, Ef 0 > 2.0 V vs. normal hydrogen electrode} in aqueous solution, reacting with PPh 3 and (PhCH2)2S to give O=PPh3 and (PhCH2)2S=O, respectively.
Persistent Identifierhttp://hdl.handle.net/10722/168182
ISSN
0022-4936
ISI Accession Number ID
WOS:A1987H963400055

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorYam, VWWen_US
dc.contributor.authorCho, KCen_US
dc.contributor.authorGray, HBen_US
dc.date.accessioned2012-10-08T03:16:02Z-
dc.date.available2012-10-08T03:16:02Z-
dc.date.issued1987en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1987 n. 12, p. 948-949en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168182-
dc.description.abstracttrans-[OsVI(tmc)(O)2]2+ (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) and trans-[Os VI(CN)4(O)2]2- are emissive in the solid state and in fluid solutions at room temperature (τ ∼ 1.0-1.5 μs); the 3Eg state of trans-[OsVI(tmc)(O) 2]2+ is a powerful one-electron oxidant {[Os VI(O)2]2+ + e- → [Os V(O)2]+, Ef 0 > 2.0 V vs. normal hydrogen electrode} in aqueous solution, reacting with PPh 3 and (PhCH2)2S to give O=PPh3 and (PhCH2)2S=O, respectively.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleMetal-oxo photo-oxidants. Photochemistry and photophysics of trans-[Os VI(tmc)(O)2]2+ (tmc = 1,4,8,11-tetramethyl-1,4, 8,11-tetra-azacyclotetradecane) and trans-[OsVI(CN) 4(O)2]2-en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39870000948en_US
dc.identifier.scopuseid_2-s2.0-37049071576en_US
dc.identifier.issue12en_US
dc.identifier.spage948en_US
dc.identifier.epage949en_US
dc.identifier.isiWOS:A1987H963400055-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridCho, KC=15129672200en_US
dc.identifier.scopusauthoridGray, HB=36047602600en_US
dc.identifier.issnl0022-4936-

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