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Article: Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN) 2(N2)]5+ from [OsVI(NH 3)4N]3+

TitleModel reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN) 2(N2)]5+ from [OsVI(NH 3)4N]3+
Authors
Che, CMLam, HWTong, WFLai, TFLau, TC
Issue Date1989
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1989 n. 24, p. 1883-1884 How to Cite?
DOI: http://dx.doi.org/10.1039/C39890001883
AbstractUV-VIS irradiation of an acetonitrile solution of [OsVI(NH 3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH 3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the μ-dinitrogen complex has been determined and the Os-N(N2) distances found to be 1.873(9) and 1.893(9) Å.
Persistent Identifierhttp://hdl.handle.net/10722/168204
ISSN
0022-4936
ISI Accession Number ID
WOS:A1989CK59600010

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorLam, HWen_US
dc.contributor.authorTong, WFen_US
dc.contributor.authorLai, TFen_US
dc.contributor.authorLau, TCen_US
dc.date.accessioned2012-10-08T03:16:14Z-
dc.date.available2012-10-08T03:16:14Z-
dc.date.issued1989en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1989 n. 24, p. 1883-1884en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168204-
dc.description.abstractUV-VIS irradiation of an acetonitrile solution of [OsVI(NH 3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH 3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the μ-dinitrogen complex has been determined and the Os-N(N2) distances found to be 1.873(9) and 1.893(9) Å.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleModel reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN) 2(N2)]5+ from [OsVI(NH 3)4N]3+en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39890001883en_US
dc.identifier.scopuseid_2-s2.0-37049075098en_US
dc.identifier.issue24en_US
dc.identifier.spage1883en_US
dc.identifier.epage1884en_US
dc.identifier.isiWOS:A1989CK59600010-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridLam, HW=23067533600en_US
dc.identifier.scopusauthoridTong, WF=15076353100en_US
dc.identifier.scopusauthoridLai, TF=7202203523en_US
dc.identifier.scopusauthoridLau, TC=7102222310en_US
dc.identifier.issnl0022-4936-

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