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Article: Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides

TitleRuthenium catalysed oxidation of alkanes with alkylhydroperoxides
Authors
Lau, TCChe, CMLee, WOPoon, CK
Issue Date1988
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1988 n. 21, p. 1406-1407 How to Cite?
DOI: http://dx.doi.org/10.1039/C39880001406
AbstractThe cis-[RuII(L)2(OH2)2] 2+ complexes (L = substituted 2,2′-bipyridines or 1,10-phenanthrolines) catalyse oxidation of saturated hydrocarbons to alcohols and ketones by t-butylhydroperoxide; the low values of kinetic isotope effect (kH/kD = 3.5 for cyclohexane) and tertiary of secondary C-H bond relative reactivities (ktert/ksec ca. 6.5 for adamantane) are in a range expected for hydrogen atom abstraction by radical species.
Persistent Identifierhttp://hdl.handle.net/10722/168211
ISSN
0022-4936
ISI Accession Number ID
WOS:A1988Q886600006

 

DC FieldValueLanguage
dc.contributor.authorLau, TCen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorLee, WOen_US
dc.contributor.authorPoon, CKen_US
dc.date.accessioned2012-10-08T03:16:19Z-
dc.date.available2012-10-08T03:16:19Z-
dc.date.issued1988en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1988 n. 21, p. 1406-1407en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168211-
dc.description.abstractThe cis-[RuII(L)2(OH2)2] 2+ complexes (L = substituted 2,2′-bipyridines or 1,10-phenanthrolines) catalyse oxidation of saturated hydrocarbons to alcohols and ketones by t-butylhydroperoxide; the low values of kinetic isotope effect (kH/kD = 3.5 for cyclohexane) and tertiary of secondary C-H bond relative reactivities (ktert/ksec ca. 6.5 for adamantane) are in a range expected for hydrogen atom abstraction by radical species.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleRuthenium catalysed oxidation of alkanes with alkylhydroperoxidesen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39880001406en_US
dc.identifier.scopuseid_2-s2.0-37049076667en_US
dc.identifier.issue21en_US
dc.identifier.spage1406en_US
dc.identifier.epage1407en_US
dc.identifier.isiWOS:A1988Q886600006-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridLau, TC=7102222310en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridLee, WO=7407087172en_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US
dc.identifier.issnl0022-4936-

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