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- Publisher Website: 10.1039/C39870001376
- Scopus: eid_2-s2.0-37049084908
- WOS: WOS:A1987K149400028
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Article: A cis-dioxoruthenium(VI) complex as active oxidant of chloride and organic substrates; preparation, characterization, and reactivity of cis-[Ru VI(6,6′-Cl2bpy)2O2] 2+ (6,6′-Cl2bpy = 6,6′-dichloro-2,2′- bipyridine)
| Title | A cis-dioxoruthenium(VI) complex as active oxidant of chloride and organic substrates; preparation, characterization, and reactivity of cis-[Ru VI(6,6′-Cl2bpy)2O2] 2+ (6,6′-Cl2bpy = 6,6′-dichloro-2,2′- bipyridine) |
|---|---|
| Authors | |
| Issue Date | 1987 |
| Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp |
| Citation | Journal Of The Chemical Society, Chemical Communications, 1987 n. 18, p. 1376-1377 How to Cite? |
| Abstract | Oxidation of cis-[RuII(6,6′-Cl2bpy) 2(OH2)2]2+ with CeIV gave cis-[RuVI(6,6′-Cl2bpy)2O 2]2+, isolated as the diamagnetic ClO4 - salt, which rapidly oxidizes Cl- (to Cl2) and a wide variety of organic substrates (tetrahydrofuran to butyrolactone and cyclohexane to cyclohexanone). |
| Persistent Identifier | http://hdl.handle.net/10722/168234 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Che, CM | en_US |
| dc.contributor.author | Leung, WH | en_US |
| dc.date.accessioned | 2012-10-08T03:16:31Z | - |
| dc.date.available | 2012-10-08T03:16:31Z | - |
| dc.date.issued | 1987 | en_US |
| dc.identifier.citation | Journal Of The Chemical Society, Chemical Communications, 1987 n. 18, p. 1376-1377 | en_US |
| dc.identifier.issn | 0022-4936 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10722/168234 | - |
| dc.description.abstract | Oxidation of cis-[RuII(6,6′-Cl2bpy) 2(OH2)2]2+ with CeIV gave cis-[RuVI(6,6′-Cl2bpy)2O 2]2+, isolated as the diamagnetic ClO4 - salt, which rapidly oxidizes Cl- (to Cl2) and a wide variety of organic substrates (tetrahydrofuran to butyrolactone and cyclohexane to cyclohexanone). | en_US |
| dc.language | eng | en_US |
| dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp | en_US |
| dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | en_US |
| dc.title | A cis-dioxoruthenium(VI) complex as active oxidant of chloride and organic substrates; preparation, characterization, and reactivity of cis-[Ru VI(6,6′-Cl2bpy)2O2] 2+ (6,6′-Cl2bpy = 6,6′-dichloro-2,2′- bipyridine) | en_US |
| dc.type | Article | en_US |
| dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
| dc.identifier.authority | Che, CM=rp00670 | en_US |
| dc.description.nature | link_to_subscribed_fulltext | en_US |
| dc.identifier.doi | 10.1039/C39870001376 | en_US |
| dc.identifier.scopus | eid_2-s2.0-37049084908 | en_US |
| dc.identifier.issue | 18 | en_US |
| dc.identifier.spage | 1376 | en_US |
| dc.identifier.epage | 1377 | en_US |
| dc.identifier.isi | WOS:A1987K149400028 | - |
| dc.publisher.place | United Kingdom | en_US |
| dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
| dc.identifier.scopusauthorid | Leung, WH=15130227700 | en_US |
| dc.identifier.issnl | 0022-4936 | - |