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- Publisher Website: 10.1039/DT9930002365
- Scopus: eid_2-s2.0-37049087990
- WOS: WOS:A1993LT04700016
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Article: Photoluminescent properties and molecular structure of [{Au(PPh3)}2(μ-bbzim)] and[{Au(PPh3)}4(μ-bbzim)][ClO4] 2(bbziM = 2,2′-bibenzimidazolate)
Title | Photoluminescent properties and molecular structure of [{Au(PPh3)}2(μ-bbzim)] and[{Au(PPh3)}4(μ-bbzim)][ClO4] 2(bbziM = 2,2′-bibenzimidazolate) |
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Authors | |
Issue Date | 1993 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
Citation | Journal Of The Chemical Society, Dalton Transactions, 1993 n. 15, p. 2365-2371 How to Cite? |
Abstract | The tetranuclear [{Au(PPh3)}4(μ-bbzim)][ClO4]2 and dinuclear [{Au(PPh3)}2(μ-bbzim)] complexes with 2,2′-bibenzimidazolate (bbzim) as bridging ligand have been characterized by X-ray crystallography. The intramolecular Au-Au separations in [{Au(PPh3)}4(μ-bbzim)][ClO4]2 are 3.157(1)-3.222(1) Å. Upon excitation at 330 nm, both complexes display intense intraligand fluorescence and phosphorescence in fluid solution at room temperature. |
Persistent Identifier | http://hdl.handle.net/10722/168243 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Tzeng, BC | en_US |
dc.contributor.author | Li, D | en_US |
dc.contributor.author | Peng, SM | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:16:37Z | - |
dc.date.available | 2012-10-08T03:16:37Z | - |
dc.date.issued | 1993 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Dalton Transactions, 1993 n. 15, p. 2365-2371 | en_US |
dc.identifier.issn | 1472-7773 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168243 | - |
dc.description.abstract | The tetranuclear [{Au(PPh3)}4(μ-bbzim)][ClO4]2 and dinuclear [{Au(PPh3)}2(μ-bbzim)] complexes with 2,2′-bibenzimidazolate (bbzim) as bridging ligand have been characterized by X-ray crystallography. The intramolecular Au-Au separations in [{Au(PPh3)}4(μ-bbzim)][ClO4]2 are 3.157(1)-3.222(1) Å. Upon excitation at 330 nm, both complexes display intense intraligand fluorescence and phosphorescence in fluid solution at room temperature. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Dalton Transactions | en_US |
dc.title | Photoluminescent properties and molecular structure of [{Au(PPh3)}2(μ-bbzim)] and[{Au(PPh3)}4(μ-bbzim)][ClO4] 2(bbziM = 2,2′-bibenzimidazolate) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/DT9930002365 | en_US |
dc.identifier.scopus | eid_2-s2.0-37049087990 | en_US |
dc.identifier.issue | 15 | en_US |
dc.identifier.spage | 2365 | en_US |
dc.identifier.epage | 2371 | en_US |
dc.identifier.isi | WOS:A1993LT04700016 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Tzeng, BC=7003648630 | en_US |
dc.identifier.scopusauthorid | Li, D=26324923700 | en_US |
dc.identifier.scopusauthorid | Peng, SM=35464852200 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 1364-5447 | - |