File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1039/DT9910001077
- Scopus: eid_2-s2.0-37049088677
- WOS: WOS:A1991FG57200020
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Inorganic excimer. Spectroscopy, photoredox properties and excimeric emission of dicyano(4,4′-di-tert-butyl-2,2′-bipyridine)platinum(II)
Title | Inorganic excimer. Spectroscopy, photoredox properties and excimeric emission of dicyano(4,4′-di-tert-butyl-2,2′-bipyridine)platinum(II) |
---|---|
Authors | |
Issue Date | 1991 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
Citation | Journal Of The Chemical Society, Dalton Transactions, 1991 n. 4, p. 1077-1080 How to Cite? |
Abstract | The complex [Pt(dtbipy)(CN)2] (dtbipy = 4,4′-di-tert-butyl-2,2′-bipyridine) has a long-lived intra-ligand (ππ*)3 excited state in fluid solutions (room-temperature lifetime at infinite dilution 3 μs in 1,2-dichloroethane). Excimer emission (maximum 565 nm) and photoinduced cligomerisation have been found for this platinum complex. The measured rate constant for the process [Pt(dtbipy)(CN)2]* + [Pt(dtbipy)(CN)2] → [{Pt(dtbipy)(CN)2}2]* is 9.0 × 108 dm3 mol-1 s-1 in 1,2-dichloroethane at room temperature. The photophysics and photoredox properties of the excited monomer and dimer are discussed. |
Persistent Identifier | http://hdl.handle.net/10722/168247 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Wan, KT | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Cho, KC | en_US |
dc.date.accessioned | 2012-10-08T03:16:38Z | - |
dc.date.available | 2012-10-08T03:16:38Z | - |
dc.date.issued | 1991 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Dalton Transactions, 1991 n. 4, p. 1077-1080 | en_US |
dc.identifier.issn | 1472-7773 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168247 | - |
dc.description.abstract | The complex [Pt(dtbipy)(CN)2] (dtbipy = 4,4′-di-tert-butyl-2,2′-bipyridine) has a long-lived intra-ligand (ππ*)3 excited state in fluid solutions (room-temperature lifetime at infinite dilution 3 μs in 1,2-dichloroethane). Excimer emission (maximum 565 nm) and photoinduced cligomerisation have been found for this platinum complex. The measured rate constant for the process [Pt(dtbipy)(CN)2]* + [Pt(dtbipy)(CN)2] → [{Pt(dtbipy)(CN)2}2]* is 9.0 × 108 dm3 mol-1 s-1 in 1,2-dichloroethane at room temperature. The photophysics and photoredox properties of the excited monomer and dimer are discussed. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Dalton Transactions | en_US |
dc.title | Inorganic excimer. Spectroscopy, photoredox properties and excimeric emission of dicyano(4,4′-di-tert-butyl-2,2′-bipyridine)platinum(II) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/DT9910001077 | en_US |
dc.identifier.scopus | eid_2-s2.0-37049088677 | en_US |
dc.identifier.issue | 4 | en_US |
dc.identifier.spage | 1077 | en_US |
dc.identifier.epage | 1080 | en_US |
dc.identifier.isi | WOS:A1991FG57200020 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Wan, KT=23069413200 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Cho, KC=15129672200 | en_US |
dc.identifier.issnl | 1364-5447 | - |