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- Publisher Website: 10.1039/C39860001519
- Scopus: eid_2-s2.0-37049089049
- WOS: WOS:A1986E558200014
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Article: Novel osmium-(V) and -(IV) dioxo complexes of macrocyclic tetradentate tertiary amines: Spectroscopic studies and reactivity of trans-[Os V(tmc)(O)2]+ (tmc = 1,4,8,11 -tetramethyl-1,4,8,11-tetra-azacyclotetradecane)
| Title | Novel osmium-(V) and -(IV) dioxo complexes of macrocyclic tetradentate tertiary amines: Spectroscopic studies and reactivity of trans-[Os V(tmc)(O)2]+ (tmc = 1,4,8,11 -tetramethyl-1,4,8,11-tetra-azacyclotetradecane) |
|---|---|
| Authors | |
| Issue Date | 1986 |
| Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp |
| Citation | Journal Of The Chemical Society, Chemical Communications, 1986 n. 20, p. 1519-1521 How to Cite? |
| Abstract | trans-[OsV(tmc)(O)2]+ (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) was generated by the electrochemical reduction of trans-[OsVI(tmc)(O)2] 2+ in MeCN with an £4 of the MeCN with an E1/2 of the OsVI/OsVcouple of -0-73 V vs. ferrocenium-ferrocene; the OsV complex displayed two vibronic structured d-d bands in the 300-450 nm region. |
| Persistent Identifier | http://hdl.handle.net/10722/168249 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Che, CM | en_US |
| dc.contributor.author | Cheng, WK | en_US |
| dc.date.accessioned | 2012-10-08T03:16:40Z | - |
| dc.date.available | 2012-10-08T03:16:40Z | - |
| dc.date.issued | 1986 | en_US |
| dc.identifier.citation | Journal Of The Chemical Society, Chemical Communications, 1986 n. 20, p. 1519-1521 | en_US |
| dc.identifier.issn | 0022-4936 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10722/168249 | - |
| dc.description.abstract | trans-[OsV(tmc)(O)2]+ (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) was generated by the electrochemical reduction of trans-[OsVI(tmc)(O)2] 2+ in MeCN with an £4 of the MeCN with an E1/2 of the OsVI/OsVcouple of -0-73 V vs. ferrocenium-ferrocene; the OsV complex displayed two vibronic structured d-d bands in the 300-450 nm region. | en_US |
| dc.language | eng | en_US |
| dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp | en_US |
| dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | en_US |
| dc.title | Novel osmium-(V) and -(IV) dioxo complexes of macrocyclic tetradentate tertiary amines: Spectroscopic studies and reactivity of trans-[Os V(tmc)(O)2]+ (tmc = 1,4,8,11 -tetramethyl-1,4,8,11-tetra-azacyclotetradecane) | en_US |
| dc.type | Article | en_US |
| dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
| dc.identifier.authority | Che, CM=rp00670 | en_US |
| dc.description.nature | link_to_subscribed_fulltext | en_US |
| dc.identifier.doi | 10.1039/C39860001519 | - |
| dc.identifier.scopus | eid_2-s2.0-37049089049 | en_US |
| dc.identifier.issue | 20 | en_US |
| dc.identifier.spage | 1519 | en_US |
| dc.identifier.epage | 1521 | en_US |
| dc.identifier.isi | WOS:A1986E558200014 | - |
| dc.publisher.place | United Kingdom | en_US |
| dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
| dc.identifier.scopusauthorid | Cheng, WK=7402169559 | en_US |
| dc.identifier.issnl | 0022-4936 | - |