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Article: Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and x-ray crystal structure of [OsO{NHC(Me) 2C(Me)2NH}{NH2C(Me)2C(Me) 2NH}]ClO4

TitleNovel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and x-ray crystal structure of [OsO{NHC(Me) 2C(Me)2NH}{NH2C(Me)2C(Me) 2NH}]ClO4
Authors
Che, CMLam, MHWWang, RJMak, TCW
Issue Date1990
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1990 n. 11, p. 820-821 How to Cite?
DOI: http://dx.doi.org/10.1039/C39900000820
AbstractThe six-co-ordinate trans-[Os(L)2(O)2]2+ [L = NH2C(Me)2C(Me)2NH2] and five-co-ordinate [OsO{NHC(Me)2C(Me)2NH}{NH 2C(Me)2C(Me)2NH}]+ complexes are in equilibrium in solution; the X-ray structure of the five-co-ordinate square pyramidal OsVI-oxo complex has been determined with a measured Os=O distance of 1.72(2) Å.
Persistent Identifierhttp://hdl.handle.net/10722/168250
ISSN
0022-4936
ISI Accession Number ID
WOS:A1990DK06400018

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorLam, MHWen_US
dc.contributor.authorWang, RJen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:16:41Z-
dc.date.available2012-10-08T03:16:41Z-
dc.date.issued1990en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1990 n. 11, p. 820-821en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168250-
dc.description.abstractThe six-co-ordinate trans-[Os(L)2(O)2]2+ [L = NH2C(Me)2C(Me)2NH2] and five-co-ordinate [OsO{NHC(Me)2C(Me)2NH}{NH 2C(Me)2C(Me)2NH}]+ complexes are in equilibrium in solution; the X-ray structure of the five-co-ordinate square pyramidal OsVI-oxo complex has been determined with a measured Os=O distance of 1.72(2) Å.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleNovel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and x-ray crystal structure of [OsO{NHC(Me) 2C(Me)2NH}{NH2C(Me)2C(Me) 2NH}]ClO4en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39900000820en_US
dc.identifier.scopuseid_2-s2.0-37049089555en_US
dc.identifier.issue11en_US
dc.identifier.spage820en_US
dc.identifier.epage821en_US
dc.identifier.isiWOS:A1990DK06400018-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridLam, MHW=7202630175en_US
dc.identifier.scopusauthoridWang, RJ=7405340385en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US
dc.identifier.issnl0022-4936-

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