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- Publisher Website: 10.1016/0009-2614(90)85625-M
- Scopus: eid_2-s2.0-4243338601
- WOS: WOS:A1990DE08800024
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Article: Kinetics of electron transfer between metal hexacyanide complexes
Title | Kinetics of electron transfer between metal hexacyanide complexes |
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Authors | |
Issue Date | 1990 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett |
Citation | Chemical Physics Letters, 1990, v. 168 n. 3-4, p. 361-364 How to Cite? |
Abstract | The electron transfer reactions between three isomorphic hexacyanides complexes, Fe(CN)6 3- 4-, Os(CN)6 3- 4- and Ru(CN)6 3- 4- have been studied using the method of photoexcitation. The electron transfer rate constants between any two complexes increase by about a factor of 60 as the ionic strength is increased from 30 to 440 mM. An ionic-strength-independent reorganization energy of 1.1 eV was found for the hexacyanide self-exchange reaction when the data were analyzed according to the theory of Marcus. © 1990. |
Persistent Identifier | http://hdl.handle.net/10722/168293 |
ISSN | 2023 Impact Factor: 2.8 2023 SCImago Journal Rankings: 0.502 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Cho, KC | en_US |
dc.contributor.author | Cham, PM | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:17:09Z | - |
dc.date.available | 2012-10-08T03:17:09Z | - |
dc.date.issued | 1990 | en_US |
dc.identifier.citation | Chemical Physics Letters, 1990, v. 168 n. 3-4, p. 361-364 | en_US |
dc.identifier.issn | 0009-2614 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168293 | - |
dc.description.abstract | The electron transfer reactions between three isomorphic hexacyanides complexes, Fe(CN)6 3- 4-, Os(CN)6 3- 4- and Ru(CN)6 3- 4- have been studied using the method of photoexcitation. The electron transfer rate constants between any two complexes increase by about a factor of 60 as the ionic strength is increased from 30 to 440 mM. An ionic-strength-independent reorganization energy of 1.1 eV was found for the hexacyanide self-exchange reaction when the data were analyzed according to the theory of Marcus. © 1990. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett | en_US |
dc.relation.ispartof | Chemical Physics Letters | en_US |
dc.title | Kinetics of electron transfer between metal hexacyanide complexes | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/0009-2614(90)85625-M | - |
dc.identifier.scopus | eid_2-s2.0-4243338601 | en_US |
dc.identifier.volume | 168 | en_US |
dc.identifier.issue | 3-4 | en_US |
dc.identifier.spage | 361 | en_US |
dc.identifier.epage | 364 | en_US |
dc.identifier.isi | WOS:A1990DE08800024 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Cho, KC=15129672200 | en_US |
dc.identifier.scopusauthorid | Cham, PM=36964387800 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 0009-2614 | - |