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Article: New chemistry with old functional groups: On the reaction of isonitriles with carboxylic acids - A route to various amide types

TitleNew chemistry with old functional groups: On the reaction of isonitriles with carboxylic acids - A route to various amide types
Authors
Li, XDanishefsky, SJ
Issue Date2008
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 2008, v. 130 n. 16, p. 5446-5448 How to Cite?
DOI: http://dx.doi.org/10.1021/ja800612r
AbstractThermolysis of isonitriles with carboxylic acids provides, in one step, N-formyl imides (see, for example, 8 + 19 → 21). The resultant N-formyl group can be converted to N-H, NCH2OH, or NCH3. This chemistry allows for a new route for synthesizing β-N (asparagine)-linked glycosyl amino acids. Copyright © 2008 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/168297
ISSN
0002-7863
2021 Impact Factor: 16.383
2020 SCImago Journal Rankings: 7.115
ISI Accession Number ID
WOS:000255041400031

 

DC FieldValueLanguage
dc.contributor.authorLi, Xen_US
dc.contributor.authorDanishefsky, SJen_US
dc.date.accessioned2012-10-08T03:17:10Z-
dc.date.available2012-10-08T03:17:10Z-
dc.date.issued2008en_US
dc.identifier.citationJournal Of The American Chemical Society, 2008, v. 130 n. 16, p. 5446-5448en_US
dc.identifier.issn0002-7863en_US
dc.identifier.urihttp://hdl.handle.net/10722/168297-
dc.description.abstractThermolysis of isonitriles with carboxylic acids provides, in one step, N-formyl imides (see, for example, 8 + 19 → 21). The resultant N-formyl group can be converted to N-H, NCH2OH, or NCH3. This chemistry allows for a new route for synthesizing β-N (asparagine)-linked glycosyl amino acids. Copyright © 2008 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_US
dc.relation.ispartofJournal of the American Chemical Societyen_US
dc.subject.meshAmides - Chemical Synthesisen_US
dc.subject.meshAsparagine - Analogs & Derivatives - Chemical Synthesisen_US
dc.subject.meshCarboxylic Acids - Chemistryen_US
dc.subject.meshGlycopeptides - Chemical Synthesisen_US
dc.subject.meshImides - Chemistryen_US
dc.subject.meshModels, Chemicalen_US
dc.subject.meshNitriles - Chemistryen_US
dc.titleNew chemistry with old functional groups: On the reaction of isonitriles with carboxylic acids - A route to various amide typesen_US
dc.typeArticleen_US
dc.identifier.emailLi, X:xuechenl@hku.hken_US
dc.identifier.authorityLi, X=rp00742en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ja800612ren_US
dc.identifier.pmid18370392-
dc.identifier.scopuseid_2-s2.0-42949170173en_US
dc.identifier.volume130en_US
dc.identifier.issue16en_US
dc.identifier.spage5446en_US
dc.identifier.epage5448en_US
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000255041400031-
dc.publisher.placeUnited Statesen_US
dc.identifier.f10001104970-
dc.identifier.scopusauthoridLi, X=24168958800en_US
dc.identifier.scopusauthoridDanishefsky, SJ=7202925243en_US
dc.identifier.issnl0002-7863-

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