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- Publisher Website: 10.1002/chem.200901895
- Scopus: eid_2-s2.0-70350233362
- PMID: 19760736
- WOS: WOS:000271605900003
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Article: Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO 2et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reaction
Title | Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO 2et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reaction |
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Authors | |
Keywords | Carbenoids Porphyrinoids Reactive intermediates Ruthenium Structure elucidation |
Issue Date | 2009 |
Publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry |
Citation | Chemistry - A European Journal, 2009, v. 15 n. 41, p. 10707-10712 How to Cite? |
Abstract | What's in my pockets? By employing Suslick's bis-pocket porphyrin (ttppp), a reactive M=CHCO 2Et complex and a trans-[M(CHR)(CO)] (M = Ru) complex have been structurally characterized by X-ray crystal analysis. The sterically encumbered ttppp ligand has a significant impact on both the diastereoselectivity and chemoselectivity in metalloporphyrin-catalyzed reactions of ethyl diazoacetate with conjugated aryl dienes. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. |
Persistent Identifier | http://hdl.handle.net/10722/168410 |
ISSN | 2023 Impact Factor: 3.9 2023 SCImago Journal Rankings: 1.058 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Deng, QH | en_HK |
dc.contributor.author | Chen, J | en_HK |
dc.contributor.author | Huang, JS | en_HK |
dc.contributor.author | Chui, SSY | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Li, GY | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2012-10-08T03:18:36Z | - |
dc.date.available | 2012-10-08T03:18:36Z | - |
dc.date.issued | 2009 | en_HK |
dc.identifier.citation | Chemistry - A European Journal, 2009, v. 15 n. 41, p. 10707-10712 | en_HK |
dc.identifier.issn | 0947-6539 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/168410 | - |
dc.description.abstract | What's in my pockets? By employing Suslick's bis-pocket porphyrin (ttppp), a reactive M=CHCO 2Et complex and a trans-[M(CHR)(CO)] (M = Ru) complex have been structurally characterized by X-ray crystal analysis. The sterically encumbered ttppp ligand has a significant impact on both the diastereoselectivity and chemoselectivity in metalloporphyrin-catalyzed reactions of ethyl diazoacetate with conjugated aryl dienes. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. | en_HK |
dc.language | eng | en_US |
dc.publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry | en_HK |
dc.relation.ispartof | Chemistry - A European Journal | en_HK |
dc.subject | Carbenoids | en_HK |
dc.subject | Porphyrinoids | en_HK |
dc.subject | Reactive intermediates | en_HK |
dc.subject | Ruthenium | en_HK |
dc.subject | Structure elucidation | en_HK |
dc.subject.mesh | Crystallography, X-Ray | en_US |
dc.subject.mesh | Methane - Analogs & Derivatives - Chemistry | en_US |
dc.subject.mesh | Molecular Conformation | en_US |
dc.subject.mesh | Molecular Structure | en_US |
dc.subject.mesh | Porphyrins - Chemical Synthesis - Chemistry | en_US |
dc.subject.mesh | Ruthenium - Chemistry | en_US |
dc.subject.mesh | Stereoisomerism | en_US |
dc.title | Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO 2et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reaction | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Huang, JS: jshuang@hku.hk | en_HK |
dc.identifier.email | Chui, SSY: chuissy@hkucc.hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.authority | Huang, JS=rp00709 | en_HK |
dc.identifier.authority | Chui, SSY=rp00686 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1002/chem.200901895 | en_HK |
dc.identifier.pmid | 19760736 | - |
dc.identifier.scopus | eid_2-s2.0-70350233362 | en_HK |
dc.identifier.hkuros | 159123 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-70350233362&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 15 | en_HK |
dc.identifier.issue | 41 | en_HK |
dc.identifier.spage | 10707 | en_HK |
dc.identifier.epage | 10712 | en_HK |
dc.identifier.eissn | 1521-3765 | - |
dc.identifier.isi | WOS:000271605900003 | - |
dc.publisher.place | Germany | en_HK |
dc.identifier.scopusauthorid | Deng, QH=8987982900 | en_HK |
dc.identifier.scopusauthorid | Chen, J=36047378100 | en_HK |
dc.identifier.scopusauthorid | Huang, JS=7407192639 | en_HK |
dc.identifier.scopusauthorid | Chui, SSY=8297453100 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Li, GY=40261792700 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 0947-6539 | - |