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Article: Efficient gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation of unactivated alkenes with ?-ketones

TitleEfficient gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation of unactivated alkenes with ?-ketones
Authors
Xiao, YPLiu, XYChe, CM
KeywordsCascade
Cocatalyzed
Gold(I)-Catalyzed
Intermolecular N-Michael Addition
Intramolecular Hydroalkylation
Pyrrolidine
Silver(I)-Catalyzed
Issue Date2011
PublisherBeilstein-Institut. The Journal's web site is located at http://www.beilstein-journals.org/bjoc/home/home.htm
Citation
Beilstein Journal Of Organic Chemistry, 2011, v. 7, p. 1100-1107 How to Cite?
DOI: http://dx.doi.org/10.3762/bjoc.7.126
AbstractThe gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation reaction offers a simple and efficient method for the synthesis of pyrrolidine derivatives in moderate to excellent product yields and with moderate to good diastereoselectivities. The reaction conditions and the substrate scope of this reaction are examined, and a possible mechanism involving AgClO4 catalyzed intermolecular N-Michael addition and the subsequent gold(I)-catalyzed hydroalkylation is proposed. © 2011 Xiao et al; licensee Beilstein-Institut.
Persistent Identifierhttp://hdl.handle.net/10722/168556
ISSN
1860-5397
2021 Impact Factor: 2.544
2020 SCImago Journal Rankings: 0.765
PubMed Central ID
PMC3170194
ISI Accession Number ID
WOS:000293790300001
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorXiao, YPen_US
dc.contributor.authorLiu, XYen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:20:34Z-
dc.date.available2012-10-08T03:20:34Z-
dc.date.issued2011en_US
dc.identifier.citationBeilstein Journal Of Organic Chemistry, 2011, v. 7, p. 1100-1107en_US
dc.identifier.issn1860-5397en_US
dc.identifier.urihttp://hdl.handle.net/10722/168556-
dc.description.abstractThe gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation reaction offers a simple and efficient method for the synthesis of pyrrolidine derivatives in moderate to excellent product yields and with moderate to good diastereoselectivities. The reaction conditions and the substrate scope of this reaction are examined, and a possible mechanism involving AgClO4 catalyzed intermolecular N-Michael addition and the subsequent gold(I)-catalyzed hydroalkylation is proposed. © 2011 Xiao et al; licensee Beilstein-Institut.en_US
dc.languageengen_US
dc.publisherBeilstein-Institut. The Journal's web site is located at http://www.beilstein-journals.org/bjoc/home/home.htm-
dc.relation.ispartofBeilstein Journal of Organic Chemistryen_US
dc.subjectCascadeen_US
dc.subjectCocatalyzeden_US
dc.subjectGold(I)-Catalyzeden_US
dc.subjectIntermolecular N-Michael Additionen_US
dc.subjectIntramolecular Hydroalkylationen_US
dc.subjectPyrrolidineen_US
dc.subjectSilver(I)-Catalyzeden_US
dc.titleEfficient gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation of unactivated alkenes with ?-ketonesen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_OA_fulltexten_US
dc.identifier.doi10.3762/bjoc.7.126en_US
dc.identifier.pmid21915213-
dc.identifier.pmcidPMC3170194-
dc.identifier.scopuseid_2-s2.0-80051775926en_US
dc.identifier.hkuros204827-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-80051775926&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume7en_US
dc.identifier.spage1100en_US
dc.identifier.epage1107en_US
dc.identifier.isiWOS:000293790300001-
dc.publisher.placeGermany-
dc.identifier.scopusauthoridXiao, YP=7403260506en_US
dc.identifier.scopusauthoridLiu, XY=47561690100en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.issnl1860-5397-

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